Zeitschrift fur Anorganische und Allgemeine Chemie, volume 638, issue 10, pages 1424-1431
Syntheses, Crystal Structures and Thermal Behavior of Five New Complexes Containing 2, 4, 6-Trifluorobenzoate as Ligand
Publication type: Journal Article
Publication date: 2012-06-27
Quartile SCImago
Q3
Quartile WOS
Q4
Impact factor: 1.4
ISSN: 00442313, 15213749, 08631786
Inorganic Chemistry
Abstract
Five new complexes containing 2, 4, 6-trifluorobenzoateas ligand have been synthesized and structurally characterized, namely Li(C6F3H2COO)(H2O) (P21, Z = 2, 1),Cs(C6F3H2COO)(C6F3H2COOH) (P21/c, Z = 4, 2),Cu(C6F3H2COO)2(H2O)2 (P, Z = 1, 3), Cu(C6F3H2COO)2(MeOH) (P21/c. Z = 4, 4) and Ag(C6F3H2COO)(H2O) (C2/c, Z = 8, 5). 1–3 and 5 are coordination polymers forming strands (1, 3, 5) or corrugated layers (2). In 1 and 2 the benzoate ligand acts as a bridging ligand, whereas in 3 and 5 the benzoate ligand is not bridging and the molecular units are interconnected by bridging water molecules. In 4 and 5, dimeric Cu2 and Ag2 units, respectively, are formed with short M···M contacts. The dimeric units in 4 resemble the well-known paddlewheel structural motif. In 5 these dimeric units are further connected by bridging water molecules, whereas in 4 only very weak F···H interactions connect the dimeric units. DTA/TG experiments on 1, 3 and 4 reveal that in a first step solvent molecules (H2O, MeOH) are unquestionably released. In 1–5 the torsion angles of the carboxylate group with respect to the aromatic ring deviate significantly from zero. These results are in very good agreement with the results of quantum chemical calculations of free 2, 4, 6-trifluorobenzoic acid and its dimer at the DFT and RI-MP2 level of theory.
Top-30
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Citations by publishers
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Wiley
7 publications, 41.18%
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Elsevier
2 publications, 11.76%
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2 publications, 11.76%
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1 publication, 5.88%
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1 publication, 5.88%
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Pleiades Publishing
1 publication, 5.88%
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Walter de Gruyter
1 publication, 5.88%
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International Union of Crystallography (IUCr)
1 publication, 5.88%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 5.88%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Lamann R. et al. Syntheses, Crystal Structures and Thermal Behavior of Five New Complexes Containing 2, 4, 6-Trifluorobenzoate as Ligand // Zeitschrift fur Anorganische und Allgemeine Chemie. 2012. Vol. 638. No. 10. pp. 1424-1431.
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Lamann R., Hülsen M., Dolg M., Ruschewitz U. Syntheses, Crystal Structures and Thermal Behavior of Five New Complexes Containing 2, 4, 6-Trifluorobenzoate as Ligand // Zeitschrift fur Anorganische und Allgemeine Chemie. 2012. Vol. 638. No. 10. pp. 1424-1431.
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TY - JOUR
DO - 10.1002/zaac.201200222
UR - https://doi.org/10.1002/zaac.201200222
TI - Syntheses, Crystal Structures and Thermal Behavior of Five New Complexes Containing 2, 4, 6-Trifluorobenzoate as Ligand
T2 - Zeitschrift fur Anorganische und Allgemeine Chemie
AU - Lamann, Rainer
AU - Hülsen, Michael
AU - Dolg, Michael
AU - Ruschewitz, U.
PY - 2012
DA - 2012/06/27 00:00:00
PB - Wiley
SP - 1424-1431
IS - 10
VL - 638
SN - 0044-2313
SN - 1521-3749
SN - 0863-1786
ER -
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@article{2012_Lamann,
author = {Rainer Lamann and Michael Hülsen and Michael Dolg and U. Ruschewitz},
title = {Syntheses, Crystal Structures and Thermal Behavior of Five New Complexes Containing 2, 4, 6-Trifluorobenzoate as Ligand},
journal = {Zeitschrift fur Anorganische und Allgemeine Chemie},
year = {2012},
volume = {638},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/zaac.201200222},
number = {10},
pages = {1424--1431},
doi = {10.1002/zaac.201200222}
}
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Lamann, Rainer, et al. “Syntheses, Crystal Structures and Thermal Behavior of Five New Complexes Containing 2, 4, 6-Trifluorobenzoate as Ligand.” Zeitschrift fur Anorganische und Allgemeine Chemie, vol. 638, no. 10, Jun. 2012, pp. 1424-1431. https://doi.org/10.1002/zaac.201200222.