Zeitschrift fur Anorganische und Allgemeine Chemie, volume 646, issue 14, pages 1260-1266
Exploring Route for Pyrophosphate-based Electrode Materials: Interplay between Synthesis and Structure
Tertov Ilya V
1
,
Mironov Andrey V
1
,
Mikheev I.V.
1
,
Drozhzhin Oleg A.
1, 2
,
Rozova Marina G
1
,
Antipov Evgeny V.
1, 2
Publication type: Journal Article
Publication date: 2020-07-16
Quartile SCImago
Q3
Quartile WOS
Q4
Impact factor: 1.4
ISSN: 00442313, 15213749, 08631786
Inorganic Chemistry
Abstract
New sodium vanadium(III) hydrogenphosphate hydrate NaV(HPO4)2(H2O)0.5 and sodium vanadium(III) hydrogenphosphate β‐NaV(HPO4)2 were prepared in mild hydrothermal conditions. The crystal structures of NaV(HPO4)2(H2O)0.5 [space group Cc, Z = 4, a = 8.46174(19) Å, b = 9.52583(19) Å, c = 8.69376(15) Å, β = 110.9553(11) °, V = 654.41(2) Å3] and β‐NaV(HPO4)2 [space group C2/c, Z = 4, a = 7.8681(3) Å, b = 9.8451(3) Å, c = 8.5180(2) Å, β = 107.626(2) °, V = 628.85(3) Å3] were solved and refined from X‐ray powder diffraction data. Both compounds were used as precursors in a new route for the preparation of attractive cathode material β‐NaVP2O7. The formation of the structure motive providing fast sodium ion diffusion at the first synthesis stage and its further conservation upon stepwise dehydration was revealed. The oversized Na+‐embedding channels are stabilized by site‐coordinated water in NaV(HPO4)2(H2O)0.5 structure. The topology resemblance and difference in known sodium vanadium(III) complex phosphates are discussed.
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Elsevier
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Multidisciplinary Digital Publishing Institute (MDPI)
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Alekseeva A. M. et al. Exploring Route for Pyrophosphate-based Electrode Materials: Interplay between Synthesis and Structure // Zeitschrift fur Anorganische und Allgemeine Chemie. 2020. Vol. 646. No. 14. pp. 1260-1266.
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Alekseeva A. M., Tertov I. V., Mironov A. V., Mikheev I., Drozhzhin O. A., Zharikova E. V., Rozova M. G., Antipov E. V. Exploring Route for Pyrophosphate-based Electrode Materials: Interplay between Synthesis and Structure // Zeitschrift fur Anorganische und Allgemeine Chemie. 2020. Vol. 646. No. 14. pp. 1260-1266.
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TY - JOUR
DO - 10.1002/zaac.202000066
UR - https://doi.org/10.1002%2Fzaac.202000066
TI - Exploring Route for Pyrophosphate-based Electrode Materials: Interplay between Synthesis and Structure
T2 - Zeitschrift fur Anorganische und Allgemeine Chemie
AU - Alekseeva, Anastasia M
AU - Tertov, Ilya V
AU - Mironov, Andrey V
AU - Zharikova, Emiliya V
AU - Rozova, Marina G
AU - Mikheev, I.V.
AU - Drozhzhin, Oleg A.
AU - Antipov, Evgeny V.
PY - 2020
DA - 2020/07/16 00:00:00
PB - Wiley
SP - 1260-1266
IS - 14
VL - 646
SN - 0044-2313
SN - 1521-3749
SN - 0863-1786
ER -
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@article{2020_Alekseeva,
author = {Anastasia M Alekseeva and Ilya V Tertov and Andrey V Mironov and Emiliya V Zharikova and Marina G Rozova and I.V. Mikheev and Oleg A. Drozhzhin and Evgeny V. Antipov},
title = {Exploring Route for Pyrophosphate-based Electrode Materials: Interplay between Synthesis and Structure},
journal = {Zeitschrift fur Anorganische und Allgemeine Chemie},
year = {2020},
volume = {646},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002%2Fzaac.202000066},
number = {14},
pages = {1260--1266},
doi = {10.1002/zaac.202000066}
}
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Alekseeva, Anastasia M., et al. “Exploring Route for Pyrophosphate-based Electrode Materials: Interplay between Synthesis and Structure.” Zeitschrift fur Anorganische und Allgemeine Chemie, vol. 646, no. 14, Jul. 2020, pp. 1260-1266. https://doi.org/10.1002%2Fzaac.202000066.