volume 142 issue 1 pages 37-44

Bimolecular Condensation of Ethanol to 1-Butanol Catalyzed by Alkali Cation Zeolites

Publication typeJournal Article
Publication date1993-07-01
scimago Q1
wos Q1
SJR1.558
CiteScore10.9
Impact factor6.5
ISSN00219517, 10902694
Catalysis
Physical and Theoretical Chemistry
Abstract
This study reports that ethanol is converted primarily into 1-butanol by a bimolecular condensation on alkali cation zeolites. For this base-catalyzed reaction, Rb-LiX exhibits the highest reaction activity and 1-butanol selectivity among zeolites employed. The reaction temperature and the contact time have a distinct influence on the condensation reactivity. It is also confirmed that the reaction does not proceed through aldol condensation. Thus, we propose a reaction mechanism in which one molecule of ethanol, whose C H bond in the β-position is activated by the basic zeolite, condenses with another molecule of ethanol by dehydration.
Found 

Top-30

Journals

1
2
3
4
5
6
7
8
9
Applied Catalysis A: General
9 publications, 8.11%
Catalysis Today
9 publications, 8.11%
ACS Catalysis
8 publications, 7.21%
Industrial & Engineering Chemistry Research
7 publications, 6.31%
ChemSusChem
6 publications, 5.41%
Journal of Catalysis
4 publications, 3.6%
Catalysis Science and Technology
4 publications, 3.6%
Green Chemistry
4 publications, 3.6%
Catalysts
3 publications, 2.7%
Applied Catalysis B: Environmental
2 publications, 1.8%
Chemical Engineering Journal
2 publications, 1.8%
Molecules
2 publications, 1.8%
Biofuels, Bioproducts and Biorefining
2 publications, 1.8%
Journal of Molecular Catalysis A Chemical
1 publication, 0.9%
Chemistry Letters
1 publication, 0.9%
Materials
1 publication, 0.9%
International Journal of Environmental Research and Public Health
1 publication, 0.9%
Nature Reviews Chemistry
1 publication, 0.9%
Biomass Conversion and Biorefinery
1 publication, 0.9%
Science China Materials
1 publication, 0.9%
Topics in Catalysis
1 publication, 0.9%
Reaction Kinetics, Mechanisms and Catalysis
1 publication, 0.9%
Applied Surface Science
1 publication, 0.9%
Journal of Oleo Science
1 publication, 0.9%
Renewable Energy
1 publication, 0.9%
Energy
1 publication, 0.9%
Journal of Cleaner Production
1 publication, 0.9%
Journal of Energy Chemistry
1 publication, 0.9%
Catalysis Communications
1 publication, 0.9%
1
2
3
4
5
6
7
8
9

Publishers

5
10
15
20
25
30
35
40
45
Elsevier
41 publications, 36.94%
American Chemical Society (ACS)
18 publications, 16.22%
Royal Society of Chemistry (RSC)
12 publications, 10.81%
Wiley
11 publications, 9.91%
MDPI
9 publications, 8.11%
Springer Nature
7 publications, 6.31%
Oxford University Press
1 publication, 0.9%
Japan Oil Chemists' Society
1 publication, 0.9%
Pleiades Publishing
1 publication, 0.9%
Taylor & Francis
1 publication, 0.9%
Walter de Gruyter
1 publication, 0.9%
Hindawi Limited
1 publication, 0.9%
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 publication, 0.9%
The Surface Science Society of Japan
1 publication, 0.9%
Science in China Press
1 publication, 0.9%
5
10
15
20
25
30
35
40
45
  • We do not take into account publications without a DOI.
  • Statistics recalculated weekly.

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
111
Share
Cite this
GOST |
Cite this
GOST Copy
Yang C., Meng Z. Y. Bimolecular Condensation of Ethanol to 1-Butanol Catalyzed by Alkali Cation Zeolites // Journal of Catalysis. 1993. Vol. 142. No. 1. pp. 37-44.
GOST all authors (up to 50) Copy
Yang C., Meng Z. Y. Bimolecular Condensation of Ethanol to 1-Butanol Catalyzed by Alkali Cation Zeolites // Journal of Catalysis. 1993. Vol. 142. No. 1. pp. 37-44.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1006/jcat.1993.1187
UR - https://doi.org/10.1006/jcat.1993.1187
TI - Bimolecular Condensation of Ethanol to 1-Butanol Catalyzed by Alkali Cation Zeolites
T2 - Journal of Catalysis
AU - Yang, Chun
AU - Meng, Z. Y.
PY - 1993
DA - 1993/07/01
PB - Elsevier
SP - 37-44
IS - 1
VL - 142
SN - 0021-9517
SN - 1090-2694
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{1993_Yang,
author = {Chun Yang and Z. Y. Meng},
title = {Bimolecular Condensation of Ethanol to 1-Butanol Catalyzed by Alkali Cation Zeolites},
journal = {Journal of Catalysis},
year = {1993},
volume = {142},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1006/jcat.1993.1187},
number = {1},
pages = {37--44},
doi = {10.1006/jcat.1993.1187}
}
MLA
Cite this
MLA Copy
Yang, Chun, and Z. Y. Meng. “Bimolecular Condensation of Ethanol to 1-Butanol Catalyzed by Alkali Cation Zeolites.” Journal of Catalysis, vol. 142, no. 1, Jul. 1993, pp. 37-44. https://doi.org/10.1006/jcat.1993.1187.