Efficient H2O2 Oxidation of Alkanes and Arenes to Alkyl Peroxides and Phenols Catalyzed by the System Vanadate-Pyrazine-2-Carboxylic Acid
Тип публикации: Journal Article
Дата публикации: 1993-07-01
scimago Q1
wos Q1
БС1
SJR: 1.558
CiteScore: 10.9
Impact factor: 6.5
ISSN: 00219517, 10902694
Catalysis
Physical and Theoretical Chemistry
Краткое описание
H 2 O 2 oxidizes cyclohexane and other alkanes in CH 3 CN at 20-70°C in the presence of the catalyst Bu 4 NVO 3 -pyrazine-2-carboxylic acid (ratio 1 : 4) to afford, after reduction with PPh 3 , the corresponding alcohol and carbonyl derivatives (the ratio decreases from 12 to 4 on raising the temperature from 20 to 70°C). The product yield reaches 46%, based on H 2 O 2 , and the turnover number is ca. 1000. The oxidation appears to give predominantly alkyl peroxides. which are partially decomposed in the course of the reaction. Peroxides can be formed when alkyl radicals, generated from alkanes, and radical-like species react with O 2 or abstract OOH groups from the vanadium complex. Benzene and its alkyl derivatives are oxidized to produce phenols as well as side-chain oxidation derivatives
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Shul'pin G. B., Attanasio D., Suber L. Efficient H2O2 Oxidation of Alkanes and Arenes to Alkyl Peroxides and Phenols Catalyzed by the System Vanadate-Pyrazine-2-Carboxylic Acid // Journal of Catalysis. 1993. Vol. 142. No. 1. pp. 147-152.
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Shul'pin G. B., Attanasio D., Suber L. Efficient H2O2 Oxidation of Alkanes and Arenes to Alkyl Peroxides and Phenols Catalyzed by the System Vanadate-Pyrazine-2-Carboxylic Acid // Journal of Catalysis. 1993. Vol. 142. No. 1. pp. 147-152.
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TY - JOUR
DO - 10.1006/jcat.1993.1196
UR - https://doi.org/10.1006/jcat.1993.1196
TI - Efficient H2O2 Oxidation of Alkanes and Arenes to Alkyl Peroxides and Phenols Catalyzed by the System Vanadate-Pyrazine-2-Carboxylic Acid
T2 - Journal of Catalysis
AU - Shul'pin, Georgiy B.
AU - Attanasio, D.
AU - Suber, L.
PY - 1993
DA - 1993/07/01
PB - Elsevier
SP - 147-152
IS - 1
VL - 142
SN - 0021-9517
SN - 1090-2694
ER -
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@article{1993_Shul'pin,
author = {Georgiy B. Shul'pin and D. Attanasio and L. Suber},
title = {Efficient H2O2 Oxidation of Alkanes and Arenes to Alkyl Peroxides and Phenols Catalyzed by the System Vanadate-Pyrazine-2-Carboxylic Acid},
journal = {Journal of Catalysis},
year = {1993},
volume = {142},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1006/jcat.1993.1196},
number = {1},
pages = {147--152},
doi = {10.1006/jcat.1993.1196}
}
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MLA
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Shul'pin, Georgiy B., et al. “Efficient H2O2 Oxidation of Alkanes and Arenes to Alkyl Peroxides and Phenols Catalyzed by the System Vanadate-Pyrazine-2-Carboxylic Acid.” Journal of Catalysis, vol. 142, no. 1, Jul. 1993, pp. 147-152. https://doi.org/10.1006/jcat.1993.1196.