Journal of Solid State Chemistry, volume 162, issue 1, pages 90-95

Ln3T2N6 (Ln=La, Ce, Pr; T=Ta, Nb), a New Family of Ternary Nitrides Isotypic to a High Tc Cuprate Superconductor

Laurent Cario ¹

Zoltán Gál ¹

Thomas Braun ¹

Francis J. DiSalvo ¹

Björn Blaschkowski ²

H.-Jürgen Meyer ²

Hide authors affiliations Show authors affiliations: 2 affiliations

Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14853-1301 |

Institut für Anorganische Chemie Universität Tübingen Auf der Morgenstelle 18 72076 Tübingen Germany |

Publication type: Journal Article

Publication date: 2001-11-01

Elsevier

Journal: Journal of Solid State Chemistry

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Quartile WOS

Impact factor: 3.3

ISSN: 00224596, 1095726X

DOI: 10.1006/jssc.2001.9359

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Materials Chemistry

Ceramics and Composites

Electronic, Optical and Magnetic Materials

Inorganic Chemistry

Physical and Theoretical Chemistry

Condensed Matter Physics

Abstract

Abstract A new family of ternary nitrides Ln3T2−xN6 (Ln=rare earth; T=Nb or Ta, 0≤x≤0.2) has been successfully synthesized using Ga or Li3N as a flux. These compounds crystallize in the tetragonal space group I4/mmm (No. 139) with parameters a≈4.05 A and c=20.2 A. They are isostructural with the high Tc superconducting cuprate La2−xSrxCaCu2O6. Extended Huckel band structure calculations show that the nitrides contain conducting TN2 layers similar to the CuO2 layers. However, magnetic measurements performed on these ternary nitrides do not show any superconducting transition down to 4 K.

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The Royal Society	The Royal Society, 1, 4% The Royal Society 1 publication, 4%
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Cario L. et al. Ln3T2N6 (Ln=La, Ce, Pr; T=Ta, Nb), a New Family of Ternary Nitrides Isotypic to a High Tc Cuprate Superconductor // Journal of Solid State Chemistry. 2001. Vol. 162. No. 1. pp. 90-95.

GOST all authors (up to 50) Copy

Cario L., Gál Z., Braun T., DiSalvo F. J., Blaschkowski B., Meyer H. Ln3T2N6 (Ln=La, Ce, Pr; T=Ta, Nb), a New Family of Ternary Nitrides Isotypic to a High Tc Cuprate Superconductor // Journal of Solid State Chemistry. 2001. Vol. 162. No. 1. pp. 90-95.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1006/jssc.2001.9359

UR - https://doi.org/10.1006/jssc.2001.9359

TI - Ln3T2N6 (Ln=La, Ce, Pr; T=Ta, Nb), a New Family of Ternary Nitrides Isotypic to a High Tc Cuprate Superconductor

T2 - Journal of Solid State Chemistry

AU - DiSalvo, Francis J.

AU - Blaschkowski, Björn

AU - Cario, Laurent

AU - Gál, Zoltán

AU - Braun, Thomas

AU - Meyer, H.-Jürgen

PY - 2001

DA - 2001/11/01 00:00:00

PB - Elsevier

SP - 90-95

IS - 1

VL - 162

SN - 0022-4596

SN - 1095-726X

ER -

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BibTex Copy

@article{2001_Cario,

author = {Francis J. DiSalvo and Björn Blaschkowski and Laurent Cario and Zoltán Gál and Thomas Braun and H.-Jürgen Meyer},

title = {Ln3T2N6 (Ln=La, Ce, Pr; T=Ta, Nb), a New Family of Ternary Nitrides Isotypic to a High Tc Cuprate Superconductor},

journal = {Journal of Solid State Chemistry},

year = {2001},

volume = {162},

publisher = {Elsevier},

month = {nov},

url = {https://doi.org/10.1006/jssc.2001.9359},

number = {1},

pages = {90--95},

doi = {10.1006/jssc.2001.9359}

}

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Cario, Laurent, et al. “Ln3T2N6 (Ln=La, Ce, Pr; T=Ta, Nb), a New Family of Ternary Nitrides Isotypic to a High Tc Cuprate Superconductor.” Journal of Solid State Chemistry, vol. 162, no. 1, Nov. 2001, pp. 90-95. https://doi.org/10.1006/jssc.2001.9359.

Found error?

Publisher

Elsevier

Journal

Journal of Solid State Chemistry

Quartile SCImago

Quartile WOS

Impact factor

3.3

ISSN

00224596 (Print)
1095726X (Electronic)