Solvation of ions, part XXX. Thermodynamics of transfer of copper ions from water to solvent mixtures
Тип публикации: Journal Article
Дата публикации: 1982-07-01
SCImago Q4
WOS Q4
БС3
SJR: 0.27
CiteScore: 2.9
Impact factor: 1.3
ISSN: 00959782, 15728927
Biochemistry
Physical and Theoretical Chemistry
Molecular Biology
Biophysics
Краткое описание
Free energies and Walden products show that the Cu+ and Ag+ ions are specifically solvated by acetonitrile (AN), 2-hydroxycyanoethane (HAN), and by pyridine (Py) whereas Na+ is specifically solvated by water, in mixtures of these organics with water. The Cu2+ ion is specifically solvated by pyridine in pyridine-water mixtures, but by water in acetonitrile-water mixtures. Ion-solvent, coordinated solvent-bulk solvent, and solvent-solvent interactions produce large entropy losses in the order Cu+≫Ag+>Na+ for transfer of these ions from water to dilute acetonitrile-water. The metallurgically important oxidations of copper, silver, CuS and Cu2 with CuSO4 in water are strongly favored in an enthalpic and free energy sense by the addition of acetonitrile, but addition of acetonitrile also produces a large loss of entropy for the reactions.
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Singh P., Macleod I. D., Parker A. J. Solvation of ions, part XXX. Thermodynamics of transfer of copper ions from water to solvent mixtures // Journal of Solution Chemistry. 1982. Vol. 11. No. 7. pp. 495-508.
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Singh P., Macleod I. D., Parker A. J. Solvation of ions, part XXX. Thermodynamics of transfer of copper ions from water to solvent mixtures // Journal of Solution Chemistry. 1982. Vol. 11. No. 7. pp. 495-508.
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TY - JOUR
DO - 10.1007/bf00647111
UR - https://doi.org/10.1007/bf00647111
TI - Solvation of ions, part XXX. Thermodynamics of transfer of copper ions from water to solvent mixtures
T2 - Journal of Solution Chemistry
AU - Singh, P.
AU - Macleod, I D
AU - Parker, A. J.
PY - 1982
DA - 1982/07/01
PB - Springer Nature
SP - 495-508
IS - 7
VL - 11
SN - 0095-9782
SN - 1572-8927
ER -
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@article{1982_Singh,
author = {P. Singh and I D Macleod and A. J. Parker},
title = {Solvation of ions, part XXX. Thermodynamics of transfer of copper ions from water to solvent mixtures},
journal = {Journal of Solution Chemistry},
year = {1982},
volume = {11},
publisher = {Springer Nature},
month = {jul},
url = {https://doi.org/10.1007/bf00647111},
number = {7},
pages = {495--508},
doi = {10.1007/bf00647111}
}
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Singh, P., et al. “Solvation of ions, part XXX. Thermodynamics of transfer of copper ions from water to solvent mixtures.” Journal of Solution Chemistry, vol. 11, no. 7, Jul. 1982, pp. 495-508. https://doi.org/10.1007/bf00647111.
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