pages 239-258

Carboxyphosphate; Predicted Chemical Properties, Synthesis and Role as an Intermediate in Enzymic Reactions

W B Knight ¹

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Department of Enzymology, Merck Sharp and Dohme Research Labs, Rahway, USA |

Publication type: Book Chapter

Publication date: 1990-01-01

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DOI: 10.1007/978-94-009-0663-1_14

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Abstract

The evidence for the existence of carboxyphosphate as a distinct chemical entity is presented. The properties predicted for this unstable mixed phosphoanhydride are discussed. The evidence for the involvement of carboxyphosphate in the reactions catalyzed by carbamoyl-phosphate synthetases, biotin carboxylases and phosphoenolpyruvate carboxylases is reviewed. The role(s) of this species in these reactions is discussed.

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