Springer Nature
Polymer Bulletin
,  том 3 ,  издание 3

Effect of (s)-(+)-ethyl-2-phenylbutanoate and poly(ethylene terephthalate) on the polymerization of propylene and 3-methyl-1-pentene over TiCl3-AlET3

Тип публикации: Journal Article
Дата публикации: 1980-01-01
Springer Nature
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БС2
SJR: 0.658
CiteScore: 6.7
Impact factor: 4.0
ISSN: 01700839, 14362449
Materials Chemistry
General Chemistry
Condensed Matter Physics
Polymers and Plastics
Краткое описание
(s)-(+)-Ethyl-2-phenylbutanoate was synthesized and polymerizations of propylene and racemic 3-methyl-1-pentene were conducted over TiCl3-AlEt3 combined with the compound. The addition of the compound caused a significant increase in the isotacticity of polypropylene as well as a substantial decrease in the activity. However, stereoelective polymerization of racemic 3-methyl-1-pentene didn't take place at all. Propylene polymerization was also carried out over TiCl3-AlEt3 by using poly(ethylene terephthalate) in place of the compound. The results obtained have led to the conclusion that these additives act mainly as reagents to reduce the concentration of AlEt3 by the formation of the complexes between AlEt3 and these additives.
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SOGA K. et al. Effect of (s)-(+)-ethyl-2-phenylbutanoate and poly(ethylene terephthalate) on the polymerization of propylene and 3-methyl-1-pentene over TiCl3-AlET3 // Polymer Bulletin. 1980. Vol. 3. No. 3.
ГОСТ со всеми авторами (до 50) Скопировать
SOGA K., Terano M., IKEDA S., Ikeda S. Effect of (s)-(+)-ethyl-2-phenylbutanoate and poly(ethylene terephthalate) on the polymerization of propylene and 3-methyl-1-pentene over TiCl3-AlET3 // Polymer Bulletin. 1980. Vol. 3. No. 3.
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TY - JOUR
DO - 10.1007/bf00254170
UR - https://doi.org/10.1007/bf00254170
TI - Effect of (s)-(+)-ethyl-2-phenylbutanoate and poly(ethylene terephthalate) on the polymerization of propylene and 3-methyl-1-pentene over TiCl3-AlET3
T2 - Polymer Bulletin
AU - SOGA, Kazuo
AU - Terano, Minoru
AU - IKEDA, Shigeru
AU - Ikeda, Sakuji
PY - 1980
DA - 1980/01/01
PB - Springer Nature
IS - 3
VL - 3
SN - 0170-0839
SN - 1436-2449
ER -
BibTex
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@article{1980_SOGA,
author = {Kazuo SOGA and Minoru Terano and Shigeru IKEDA and Sakuji Ikeda},
title = {Effect of (s)-(+)-ethyl-2-phenylbutanoate and poly(ethylene terephthalate) on the polymerization of propylene and 3-methyl-1-pentene over TiCl3-AlET3},
journal = {Polymer Bulletin},
year = {1980},
volume = {3},
publisher = {Springer Nature},
month = {jan},
url = {https://doi.org/10.1007/bf00254170},
number = {3},
doi = {10.1007/bf00254170}
}