Vibrational spectral studies of ion-ion and ion-solvent interactions. II. Zinc nitrate in water/dioxane mixtures
Тип публикации: Journal Article
Дата публикации: 1978-06-01
scimago Q3
wos Q4
white level БС3
SJR: 0.279
CiteScore: 2.3
Impact factor: 1.3
ISSN: 00959782, 15728927
Biochemistry
Physical and Theoretical Chemistry
Molecular Biology
Biophysics
Краткое описание
Raman and infrared spectral data have been collected forp-dioxane and solvated and bound nitrate ions for Zn(NO3)2/p-dioxane/water systems. It is concluded that Zn2+ is preferentially solvated by water and that this aquation is also responsible for a lower concentration of ion pairs than is found for methanol/Zn(NO3)2 solutions for which the dielectric constant of the bulk solvent is similar. Values of K1 (M−1), the association constant for Zn(NO3)+, are 0.22±0.02 (2/1 solvent,D=12.6) and 0.071±0.01 (4/1 solvent,D=33.0). The log K1 against 1/D plot is not linear.
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Sze Y., Irish D. E. Vibrational spectral studies of ion-ion and ion-solvent interactions. II. Zinc nitrate in water/dioxane mixtures // Journal of Solution Chemistry. 1978. Vol. 7. No. 6. pp. 417-432.
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Sze Y., Irish D. E. Vibrational spectral studies of ion-ion and ion-solvent interactions. II. Zinc nitrate in water/dioxane mixtures // Journal of Solution Chemistry. 1978. Vol. 7. No. 6. pp. 417-432.
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TY - JOUR
DO - 10.1007/bf00646112
UR - https://doi.org/10.1007/bf00646112
TI - Vibrational spectral studies of ion-ion and ion-solvent interactions. II. Zinc nitrate in water/dioxane mixtures
T2 - Journal of Solution Chemistry
AU - Sze, Yu-Keung
AU - Irish, Donald E
PY - 1978
DA - 1978/06/01
PB - Springer Nature
SP - 417-432
IS - 6
VL - 7
SN - 0095-9782
SN - 1572-8927
ER -
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BibTex (до 50 авторов)
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@article{1978_Sze,
author = {Yu-Keung Sze and Donald E Irish},
title = {Vibrational spectral studies of ion-ion and ion-solvent interactions. II. Zinc nitrate in water/dioxane mixtures},
journal = {Journal of Solution Chemistry},
year = {1978},
volume = {7},
publisher = {Springer Nature},
month = {jun},
url = {https://doi.org/10.1007/bf00646112},
number = {6},
pages = {417--432},
doi = {10.1007/bf00646112}
}
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MLA
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Sze, Yu-Keung, and Donald E Irish. “Vibrational spectral studies of ion-ion and ion-solvent interactions. II. Zinc nitrate in water/dioxane mixtures.” Journal of Solution Chemistry, vol. 7, no. 6, Jun. 1978, pp. 417-432. https://doi.org/10.1007/bf00646112.
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