Tetraethylammonium acetate tetrahydrate, (C2H5)4N+ CH3COO? � 4H2O, a layer structure with cations sandwiched between nets of puckered polygons formed by hydrogen-bonded anions and water molecules
Publication type: Journal Article
Publication date: 1986-09-01
scimago Q3
wos Q3
SJR: 0.364
CiteScore: 3.7
Impact factor: 1.6
ISSN: 13883127, 15731111, 09230750
General Chemistry
Condensed Matter Physics
Food Science
Abstract
Crystals of (C2H5)4N+ CH3COOO− · 4H2O crystallize in space groupP ī, witha=12.327(2),b=17.196(6),c=8.753(3) Å, α=94.28(2), β=91.09(2), γ=120.30(2)°, andZ=4. The structure was solved by direct methods and refined toR F -0.060 for 4803 MoKα data. In the crystal structure, ordered (C2H5)4N+ cations are sandwiched between puckered layers of hydrogen-bonded water molecules and acetate anions. Each wateranion layer is constructed from an edge-sharing assembly of six independent, irregular, and non-planar polygons (two nonagons, two hexagons and two pentagons). All protons in the scheme of hydrogen bonding are uniquely located.
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Mak T. C. W. Tetraethylammonium acetate tetrahydrate, (C2H5)4N+ CH3COO? � 4H2O, a layer structure with cations sandwiched between nets of puckered polygons formed by hydrogen-bonded anions and water molecules // Journal of Inclusion Phenomena and Macrocyclic Chemistry. 1986. Vol. 4. No. 3. pp. 273-280.
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Mak T. C. W. Tetraethylammonium acetate tetrahydrate, (C2H5)4N+ CH3COO? � 4H2O, a layer structure with cations sandwiched between nets of puckered polygons formed by hydrogen-bonded anions and water molecules // Journal of Inclusion Phenomena and Macrocyclic Chemistry. 1986. Vol. 4. No. 3. pp. 273-280.
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TY - JOUR
DO - 10.1007/bf00658001
UR - https://doi.org/10.1007/bf00658001
TI - Tetraethylammonium acetate tetrahydrate, (C2H5)4N+ CH3COO? � 4H2O, a layer structure with cations sandwiched between nets of puckered polygons formed by hydrogen-bonded anions and water molecules
T2 - Journal of Inclusion Phenomena and Macrocyclic Chemistry
AU - Mak, Thomas C. W.
PY - 1986
DA - 1986/09/01
PB - Springer Nature
SP - 273-280
IS - 3
VL - 4
SN - 1388-3127
SN - 1573-1111
SN - 0923-0750
ER -
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@article{1986_Mak,
author = {Thomas C. W. Mak},
title = {Tetraethylammonium acetate tetrahydrate, (C2H5)4N+ CH3COO? � 4H2O, a layer structure with cations sandwiched between nets of puckered polygons formed by hydrogen-bonded anions and water molecules},
journal = {Journal of Inclusion Phenomena and Macrocyclic Chemistry},
year = {1986},
volume = {4},
publisher = {Springer Nature},
month = {sep},
url = {https://doi.org/10.1007/bf00658001},
number = {3},
pages = {273--280},
doi = {10.1007/bf00658001}
}
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Mak, Thomas C. W.. “Tetraethylammonium acetate tetrahydrate, (C2H5)4N+ CH3COO? � 4H2O, a layer structure with cations sandwiched between nets of puckered polygons formed by hydrogen-bonded anions and water molecules.” Journal of Inclusion Phenomena and Macrocyclic Chemistry, vol. 4, no. 3, Sep. 1986, pp. 273-280. https://doi.org/10.1007/bf00658001.