Russian Chemical Bulletin, volume 45, issue 9, pages 2101-2104
Mechanism of the monomolecular thermal decomposition of tetrazole and 5-substituted tetrazoles
Publication type: Journal Article
Publication date: 1996-09-01
Journal:
Russian Chemical Bulletin
Quartile SCImago
Q3
Quartile WOS
Q3
SJR: 0.292
CiteScore: 2.7
Impact factor: 1.7
ISSN: 10665285, 15739171
General Chemistry
Abstract
The kinetic parameters of the thermal decomposition of tetrazole and 5-alkyl- and 5-aryl-substituted tetrazoles in melts of neat substances and in nitrobenzene solutions have been determined using the manometric method. The limiting stages of the monomolecular decomposition, which determine the observed rate of nitrogen formation, include the fast reversible transformation of the lH- and 2H-forms and the reversible opening of the 2H-form followed by the formation and subsequent cleavage of the corresponding intermediate diazo compound.
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Prokudin V. G., Poplavsky V. S., Ostrovskii V. A. Mechanism of the monomolecular thermal decomposition of tetrazole and 5-substituted tetrazoles // Russian Chemical Bulletin. 1996. Vol. 45. No. 9. pp. 2101-2104.
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Prokudin V. G., Poplavsky V. S., Ostrovskii V. A. Mechanism of the monomolecular thermal decomposition of tetrazole and 5-substituted tetrazoles // Russian Chemical Bulletin. 1996. Vol. 45. No. 9. pp. 2101-2104.
Cite this
RIS
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TY - JOUR
DO - 10.1007/bf01430718
UR - https://doi.org/10.1007/bf01430718
TI - Mechanism of the monomolecular thermal decomposition of tetrazole and 5-substituted tetrazoles
T2 - Russian Chemical Bulletin
AU - Prokudin, V G
AU - Poplavsky, V S
AU - Ostrovskii, V A
PY - 1996
DA - 1996/09/01
PB - Springer Nature
SP - 2101-2104
IS - 9
VL - 45
SN - 1066-5285
SN - 1573-9171
ER -
Cite this
BibTex
Copy
@article{1996_Prokudin,
author = {V G Prokudin and V S Poplavsky and V A Ostrovskii},
title = {Mechanism of the monomolecular thermal decomposition of tetrazole and 5-substituted tetrazoles},
journal = {Russian Chemical Bulletin},
year = {1996},
volume = {45},
publisher = {Springer Nature},
month = {sep},
url = {https://doi.org/10.1007/bf01430718},
number = {9},
pages = {2101--2104},
doi = {10.1007/bf01430718}
}
Cite this
MLA
Copy
Prokudin, V. G., et al. “Mechanism of the monomolecular thermal decomposition of tetrazole and 5-substituted tetrazoles.” Russian Chemical Bulletin, vol. 45, no. 9, Sep. 1996, pp. 2101-2104. https://doi.org/10.1007/bf01430718.