Polymer Bulletin

, volume 78 , issue 3 , pages 1573-1584

Epoxy polymers modified with polyetherimide. Part I: rheological and thermomechanical characteristics

Roman Korokhin ¹

A V Shapagin ²

V. I. Solodilov ¹

U G Zvereva ¹

D V Solomatin ¹

Yu. A. Gorbatkina ¹

Hide authors affiliations Show authors affiliations: 2 affiliations

Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russia |

Frumkin Institute of Physical Chemistry and electrochemistry, Russian Academy of Sciences, Moscow, Russia |

Publication type: Journal Article

Publication date: 2020-03-25

Springer Nature

Polymer Bulletin

scimago Q2

wos Q2

SJR: 0.658

CiteScore: 6.7

Impact factor: 4.0

ISSN: 01700839, 14362449

DOI: 10.1007/s00289-020-03174-8

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Materials Chemistry

General Chemistry

Condensed Matter Physics

Polymers and Plastics

Abstract

Using the methods of viscometry, SEM, DMA the effect of polyetherimide (PEI) on the properties of ED-20 epoxy oligomer during and after curing was studied. It was shown that the introduction of the modifier significantly affects the kinetics of curing process and the structure of epoxy–polyetherimide matrices. The introduction of PEI reduces the curing time of epoxy resin blends. With increasing temperature, the curing time, working life and gel time of all compositions are reduced by an order. In homogeneous epoxy/PEI compositions, phase separation occurs during curing. It was found that with an increase in the PEI concentration to 25 parts by mass, the matrix-dispersion type of structure with PEI-rich particles and epoxy-rich continuous phase changes to a complex bicontinuous structure. The Young modulus of the cured compositions differs by no more than 15%, and the glass transition temperature (Tg) of the matrix with the addition of PEI increases.

Found

1 citation

Khasbiullin Ramil

PhD in Chemistry

23 publications, 124 citations, 4 reviews

h-index: 7

A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

Research interests

Thermal analysis

1 citation

Nikulova Uliana

PhD in Chemistry

26 publications, 100 citations, 1 review

h-index: 6

A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

Research interests

Polymer science

1 citation

Khina Alexander

13 publications, 74 citations

h-index: 5

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Korokhin R. et al. Epoxy polymers modified with polyetherimide. Part I: rheological and thermomechanical characteristics // Polymer Bulletin. 2020. Vol. 78. No. 3. pp. 1573-1584.

GOST all authors (up to 50) Copy

Korokhin R., Shapagin A. V., Solodilov V. I., Zvereva U. G., Solomatin D. V., Gorbatkina Y. A. Epoxy polymers modified with polyetherimide. Part I: rheological and thermomechanical characteristics // Polymer Bulletin. 2020. Vol. 78. No. 3. pp. 1573-1584.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1007/s00289-020-03174-8

UR - https://doi.org/10.1007/s00289-020-03174-8

TI - Epoxy polymers modified with polyetherimide. Part I: rheological and thermomechanical characteristics

T2 - Polymer Bulletin

AU - Korokhin, Roman

AU - Shapagin, A V

AU - Solodilov, V. I.

AU - Zvereva, U G

AU - Solomatin, D V

AU - Gorbatkina, Yu. A.

PY - 2020

DA - 2020/03/25

PB - Springer Nature

SP - 1573-1584

IS - 3

VL - 78

SN - 0170-0839

SN - 1436-2449

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2020_Korokhin,

author = {Roman Korokhin and A V Shapagin and V. I. Solodilov and U G Zvereva and D V Solomatin and Yu. A. Gorbatkina},

title = {Epoxy polymers modified with polyetherimide. Part I: rheological and thermomechanical characteristics},

journal = {Polymer Bulletin},

year = {2020},

volume = {78},

publisher = {Springer Nature},

month = {mar},

url = {https://doi.org/10.1007/s00289-020-03174-8},

number = {3},

pages = {1573--1584},

doi = {10.1007/s00289-020-03174-8}

}

MLA

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MLA Copy

Korokhin, Roman, et al. “Epoxy polymers modified with polyetherimide. Part I: rheological and thermomechanical characteristics.” Polymer Bulletin, vol. 78, no. 3, Mar. 2020, pp. 1573-1584. https://doi.org/10.1007/s00289-020-03174-8.

Publisher

Springer Nature

Journal

Polymer Bulletin

scimago Q2

wos Q2

SJR

0.658

CiteScore

6.7

Impact factor

4.0

ISSN

01700839 (Print)

14362449 (Electronic)

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