Absolute Configuration of Stizolicin and Synthesis and Biological Activity of Its Amino Derivatives
E M Suleimenov
1
,
V.A. Raldugin
2
,
Yu.V Gatilov
2
,
I. Yu. Bagryanskaya
2
,
R Seidakhmetova
1
,
R M Aksartov
1
,
S M Adekenov
1
1
Institute of Phytochemistry, Ministry of Education and Science of the Republic of Kazakhstan, Karaganda, Republic of Kazakhstan
|
Publication type: Journal Article
Publication date: 2005-09-01
scimago Q3
wos Q4
SJR: 0.296
CiteScore: 1.3
Impact factor: 0.9
ISSN: 00093130, 15738388
General Chemistry
General Biochemistry, Genetics and Molecular Biology
Plant Science
Abstract
Reaction of the germacranolide stizolicin with secondary amines formed normal products of a Michael reaction at the exomethylene group and simultaneously led to solvolysis with cleavage of the acyl group. The structures of the molecules were established by XSA. Use of the HI salt of one of the resulting amines enabled the proof of its absolute configuration and that of the starting stizolicin, which had previously only been proposed. Stizolicin and the synthesized compounds were screened for antimicrobial and antitrichomonal activity.
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Suleimenov E. M. et al. Absolute Configuration of Stizolicin and Synthesis and Biological Activity of Its Amino Derivatives // Chemistry of Natural Compounds. 2005. Vol. 41. No. 5. pp. 561-564.
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Suleimenov E. M., Raldugin V., Gatilov Y., Bagryanskaya I. Y., Seidakhmetova R., Aksartov R. M., Adekenov S. M. Absolute Configuration of Stizolicin and Synthesis and Biological Activity of Its Amino Derivatives // Chemistry of Natural Compounds. 2005. Vol. 41. No. 5. pp. 561-564.
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RIS
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TY - JOUR
DO - 10.1007/s10600-005-0206-8
UR - https://doi.org/10.1007/s10600-005-0206-8
TI - Absolute Configuration of Stizolicin and Synthesis and Biological Activity of Its Amino Derivatives
T2 - Chemistry of Natural Compounds
AU - Suleimenov, E M
AU - Raldugin, V.A.
AU - Gatilov, Yu.V
AU - Bagryanskaya, I. Yu.
AU - Seidakhmetova, R
AU - Aksartov, R M
AU - Adekenov, S M
PY - 2005
DA - 2005/09/01
PB - Springer Nature
SP - 561-564
IS - 5
VL - 41
SN - 0009-3130
SN - 1573-8388
ER -
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BibTex (up to 50 authors)
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@article{2005_Suleimenov,
author = {E M Suleimenov and V.A. Raldugin and Yu.V Gatilov and I. Yu. Bagryanskaya and R Seidakhmetova and R M Aksartov and S M Adekenov},
title = {Absolute Configuration of Stizolicin and Synthesis and Biological Activity of Its Amino Derivatives},
journal = {Chemistry of Natural Compounds},
year = {2005},
volume = {41},
publisher = {Springer Nature},
month = {sep},
url = {https://doi.org/10.1007/s10600-005-0206-8},
number = {5},
pages = {561--564},
doi = {10.1007/s10600-005-0206-8}
}
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MLA
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Suleimenov, E. M., et al. “Absolute Configuration of Stizolicin and Synthesis and Biological Activity of Its Amino Derivatives.” Chemistry of Natural Compounds, vol. 41, no. 5, Sep. 2005, pp. 561-564. https://doi.org/10.1007/s10600-005-0206-8.