Springer Nature
Journal of Radioanalytical and Nuclear Chemistry
,  volume 333 ,  issue 10 ,  pages 4971-4982

Effect of substituted cobalt–chromium–iron oxides’ dissolution kinetics in oxidizing formulation on decontamination process

Publication type: Journal Article
Publication date: 2024-07-16
Springer Nature
scimago Q2
wos Q3
SJR: 0.388
CiteScore: 2.9
Impact factor: 1.6
ISSN: 02365731, 15882780
Abstract

Removing radioactive corrosion products from Cr-containing iron oxides require a multi-step and multi-cycle decontamination process. The present article brings out the effect of divalent metal ion substitution on the release rate of chromium in the oxidative pre-treatment step. The non-stoichiometric cobalt chromium ferrites were synthesized, characterized and effect of Zn2+/Ni2+ substitution on the dissolution behavior was probed. The dissolution rates decreased with increasing the degree of inclusion and showed minima at ~ 0.4–0.6 atom% which is explained on the basis of lattice structure. It is concluded that the dissolution kinetics of native nickel–chromium ferrites in reactors increases with metal ion inclusion.

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Balaji V. et al. Effect of substituted cobalt–chromium–iron oxides’ dissolution kinetics in oxidizing formulation on decontamination process // Journal of Radioanalytical and Nuclear Chemistry. 2024. Vol. 333. No. 10. pp. 4971-4982.
GOST all authors (up to 50) Copy
Balaji V., Chandramohan P., Rajesh P., Bera S., Mohan T. V. K. Effect of substituted cobalt–chromium–iron oxides’ dissolution kinetics in oxidizing formulation on decontamination process // Journal of Radioanalytical and Nuclear Chemistry. 2024. Vol. 333. No. 10. pp. 4971-4982.
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RIS Copy
TY - JOUR
DO - 10.1007/s10967-024-09650-z
UR - https://link.springer.com/10.1007/s10967-024-09650-z
TI - Effect of substituted cobalt–chromium–iron oxides’ dissolution kinetics in oxidizing formulation on decontamination process
T2 - Journal of Radioanalytical and Nuclear Chemistry
AU - Balaji, V.
AU - Chandramohan, P.
AU - Rajesh, Puspalata
AU - Bera, Santanu
AU - Mohan, T V Krishna
PY - 2024
DA - 2024/07/16
PB - Springer Nature
SP - 4971-4982
IS - 10
VL - 333
SN - 0236-5731
SN - 1588-2780
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2024_Balaji,
author = {V. Balaji and P. Chandramohan and Puspalata Rajesh and Santanu Bera and T V Krishna Mohan},
title = {Effect of substituted cobalt–chromium–iron oxides’ dissolution kinetics in oxidizing formulation on decontamination process},
journal = {Journal of Radioanalytical and Nuclear Chemistry},
year = {2024},
volume = {333},
publisher = {Springer Nature},
month = {jul},
url = {https://link.springer.com/10.1007/s10967-024-09650-z},
number = {10},
pages = {4971--4982},
doi = {10.1007/s10967-024-09650-z}
}
MLA
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MLA Copy
Balaji, V., et al. “Effect of substituted cobalt–chromium–iron oxides’ dissolution kinetics in oxidizing formulation on decontamination process.” Journal of Radioanalytical and Nuclear Chemistry, vol. 333, no. 10, Jul. 2024, pp. 4971-4982. https://link.springer.com/10.1007/s10967-024-09650-z.