Vicarious Nucleophilic C-Amination of Nitrobenzene and 5- and 6-Nitro-1-methylbenzimidazoles
Publication type: Journal Article
Publication date: 2005-09-01
scimago Q4
wos Q4
SJR: 0.190
CiteScore: 1.3
Impact factor: 0.9
ISSN: 10704280, 16083393
Organic Chemistry
Abstract
Vicarious nucleophilic C-amination of nitrobenzene, 1-methyl-5-nitrobenzimidazole, and 1-methyl-6-nitrobenzimidazole in superbasic medium (potassium tert-butoxide-dimethyl sulfoxide) gave the corresponding amino-substituted derivatives. The yield of the amination product of 1-methyl-5-nitrobenzimidazole considerably increased in the presence of CuCl. ESR monitoring of these reactions revealed formation of primary radical anions from the substrates. Possible reaction mechanisms are discussed.
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Total citations:
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Citations from 2024:
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GOST
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TITOVA I. et al. Vicarious Nucleophilic C-Amination of Nitrobenzene and 5- and 6-Nitro-1-methylbenzimidazoles // Russian Journal of Organic Chemistry. 2005. Vol. 41. No. 9. pp. 1306-1315.
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TITOVA I., Vakulskaya T. I., Larina L. I., Mizandrontsev M. I., Volkov V. A., Dolgushin G. V., Lopyrev V. Vicarious Nucleophilic C-Amination of Nitrobenzene and 5- and 6-Nitro-1-methylbenzimidazoles // Russian Journal of Organic Chemistry. 2005. Vol. 41. No. 9. pp. 1306-1315.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1007/s11178-005-0339-z
UR - https://doi.org/10.1007/s11178-005-0339-z
TI - Vicarious Nucleophilic C-Amination of Nitrobenzene and 5- and 6-Nitro-1-methylbenzimidazoles
T2 - Russian Journal of Organic Chemistry
AU - TITOVA, I.A.
AU - Vakulskaya, T I
AU - Larina, L I
AU - Mizandrontsev, M I
AU - Volkov, V. A.
AU - Dolgushin, G V
AU - Lopyrev, V.A
PY - 2005
DA - 2005/09/01
PB - Pleiades Publishing
SP - 1306-1315
IS - 9
VL - 41
SN - 1070-4280
SN - 1608-3393
ER -
Cite this
BibTex (up to 50 authors)
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@article{2005_TITOVA,
author = {I.A. TITOVA and T I Vakulskaya and L I Larina and M I Mizandrontsev and V. A. Volkov and G V Dolgushin and V.A Lopyrev},
title = {Vicarious Nucleophilic C-Amination of Nitrobenzene and 5- and 6-Nitro-1-methylbenzimidazoles},
journal = {Russian Journal of Organic Chemistry},
year = {2005},
volume = {41},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1007/s11178-005-0339-z},
number = {9},
pages = {1306--1315},
doi = {10.1007/s11178-005-0339-z}
}
Cite this
MLA
Copy
TITOVA, I.A., et al. “Vicarious Nucleophilic C-Amination of Nitrobenzene and 5- and 6-Nitro-1-methylbenzimidazoles.” Russian Journal of Organic Chemistry, vol. 41, no. 9, Sep. 2005, pp. 1306-1315. https://doi.org/10.1007/s11178-005-0339-z.