Crown-ether styryl dyes: 15. Synthesis and two pathways of regio- and stereospecific cation-dependent [2+2]-autophotocycloaddition of chromogenic 15-crown-5-ether betaines of quinoline series
Тип публикации: Journal Article
Дата публикации: 1995-11-01
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SJR: 0.305
CiteScore: 2.8
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ISSN: 10665285, 15739171
General Chemistry
Краткое описание
Styryl dyes (4a,b) containing a 15-crown-5 fragment and isomeric 2- and 4-quinolinium residues with anN-sulfopropyl substituent undergo [2+2]-autophotocycloaddition to give cyclobutane derivatives (9a,b) in acetonitrile only in the presence of Mg(ClO4)2 or Ca(ClO4)2. The stereospecificity of both pathways of photocycloaddition and its efficiency are explained by the preorganization of the supramolecular dimers derived from thetrans-isomers of the dyes when they are bound into complexes with Mg and Ca cations.
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Gromov S. P. et al. Crown-ether styryl dyes: 15. Synthesis and two pathways of regio- and stereospecific cation-dependent [2+2]-autophotocycloaddition of chromogenic 15-crown-5-ether betaines of quinoline series // Russian Chemical Bulletin. 1995. Vol. 44. No. 11. pp. 2131-2136.
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Gromov S. P., Fedorova O., Ushakov E. N., Buevich A. V., Alfimov M. Crown-ether styryl dyes: 15. Synthesis and two pathways of regio- and stereospecific cation-dependent [2+2]-autophotocycloaddition of chromogenic 15-crown-5-ether betaines of quinoline series // Russian Chemical Bulletin. 1995. Vol. 44. No. 11. pp. 2131-2136.
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TY - JOUR
DO - 10.1007/BF00696719
UR - http://link.springer.com/10.1007/BF00696719
TI - Crown-ether styryl dyes: 15. Synthesis and two pathways of regio- and stereospecific cation-dependent [2+2]-autophotocycloaddition of chromogenic 15-crown-5-ether betaines of quinoline series
T2 - Russian Chemical Bulletin
AU - Gromov, S P
AU - Fedorova, O.A.
AU - Ushakov, E N
AU - Buevich, A V
AU - Alfimov, M.V.
PY - 1995
DA - 1995/11/01
PB - Springer Nature
SP - 2131-2136
IS - 11
VL - 44
SN - 1066-5285
SN - 1573-9171
ER -
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@article{1995_Gromov,
author = {S P Gromov and O.A. Fedorova and E N Ushakov and A V Buevich and M.V. Alfimov},
title = {Crown-ether styryl dyes: 15. Synthesis and two pathways of regio- and stereospecific cation-dependent [2+2]-autophotocycloaddition of chromogenic 15-crown-5-ether betaines of quinoline series},
journal = {Russian Chemical Bulletin},
year = {1995},
volume = {44},
publisher = {Springer Nature},
month = {nov},
url = {http://link.springer.com/10.1007/BF00696719},
number = {11},
pages = {2131--2136},
doi = {10.1007/BF00696719}
}
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Gromov, S. P., et al. “Crown-ether styryl dyes: 15. Synthesis and two pathways of regio- and stereospecific cation-dependent [2+2]-autophotocycloaddition of chromogenic 15-crown-5-ether betaines of quinoline series.” Russian Chemical Bulletin, vol. 44, no. 11, Nov. 1995, pp. 2131-2136. http://link.springer.com/10.1007/BF00696719.