volume 40 issue 6 pages 1229-1234

Catalytic synthesis and transformations of magnesium-cycloalkanes. 1. New catalytic transformations in the series of magnesium-cyclopentanes

Publication typeJournal Article
Publication date1991-06-01
scimago Q3
SJR0.305
CiteScore2.8
Impact factor
ISSN10665285, 15739171
General Chemistry
Abstract
The reactions of magnesium-cyclopentane with styrene and of 2,4-diphenylmagnesium-cyclopentane with ethylene in the presence of catalytic amounts of Cp2-ZrCl2 leading to the formation of 2-phenylmagnesium-cyclopentane and 2,4-di-phenylmagnesium-cycloheptane, were studied for the first time. It was found that zirconocyclopentanes, are intermediates in this reaction, which are formed both from magnesium-cycloalkanes and from α-olefins and Cp2ZrCl2. A possible mechanism of the reactions studied has been proposed.
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GOST Copy
Dzhemilev U. M. et al. Catalytic synthesis and transformations of magnesium-cycloalkanes. 1. New catalytic transformations in the series of magnesium-cyclopentanes // Russian Chemical Bulletin. 1991. Vol. 40. No. 6. pp. 1229-1234.
GOST all authors (up to 50) Copy
Dzhemilev U. M., Sultanov R. M., Gaimaldinov R. G., Tolstikov G. Catalytic synthesis and transformations of magnesium-cycloalkanes. 1. New catalytic transformations in the series of magnesium-cyclopentanes // Russian Chemical Bulletin. 1991. Vol. 40. No. 6. pp. 1229-1234.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1007/bf00961303
UR - https://doi.org/10.1007/bf00961303
TI - Catalytic synthesis and transformations of magnesium-cycloalkanes. 1. New catalytic transformations in the series of magnesium-cyclopentanes
T2 - Russian Chemical Bulletin
AU - Dzhemilev, U M
AU - Sultanov, R M
AU - Gaimaldinov, R G
AU - Tolstikov, G.A.
PY - 1991
DA - 1991/06/01
PB - Springer Nature
SP - 1229-1234
IS - 6
VL - 40
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{1991_Dzhemilev,
author = {U M Dzhemilev and R M Sultanov and R G Gaimaldinov and G.A. Tolstikov},
title = {Catalytic synthesis and transformations of magnesium-cycloalkanes. 1. New catalytic transformations in the series of magnesium-cyclopentanes},
journal = {Russian Chemical Bulletin},
year = {1991},
volume = {40},
publisher = {Springer Nature},
month = {jun},
url = {https://doi.org/10.1007/bf00961303},
number = {6},
pages = {1229--1234},
doi = {10.1007/bf00961303}
}
MLA
Cite this
MLA Copy
Dzhemilev, U. M., et al. “Catalytic synthesis and transformations of magnesium-cycloalkanes. 1. New catalytic transformations in the series of magnesium-cyclopentanes.” Russian Chemical Bulletin, vol. 40, no. 6, Jun. 1991, pp. 1229-1234. https://doi.org/10.1007/bf00961303.