Solvent extraction of metals with macrocyclic compounds. I - The use of 15-membered compounds with donor system 2N, 20
Publication type: Journal Article
Publication date: 1984-09-01
scimago Q1
wos Q1
SJR: 0.833
CiteScore: 7.8
Impact factor: 5.3
ISSN: 00263672, 14365073
Analytical Chemistry
Abstract
The extractants studied in this work are 5,6; 14,15-dibenzo-l,4-dioxa-8,12-diazacyclopentadeca-7,12-diene (I) and 5,6; 14,15-dibenzo-1,4-dioxa-8,12-diazacyclopentadecane (II). Radioactive nuclides were used to investigate the extraction of Ag(I), Hg(II), Cu(II), Cd, Co(II), Zn, Fe(III), Mn(II), and Pd with chloroform solutions of I and II. It is shown that compound I extracts only silver. The composition of the extracted compound has been established: silver is extracted as an AgLX complexe (L being macrocycle I and X being the counterion). The counterions involved in the experiment were perchlorate, picrate (Pi), and dipicrylaminate (DPA); the extraction of silver is intensified in the series: ClO4 −
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Morosanova E. I. et al. Solvent extraction of metals with macrocyclic compounds. I - The use of 15-membered compounds with donor system 2N, 20 // Microchimica Acta. 1984. Vol. 84. No. 5-6. pp. 389-397.
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Morosanova E. I., Zolotov Y., Bodnya V. A., Formanovsky A. Solvent extraction of metals with macrocyclic compounds. I - The use of 15-membered compounds with donor system 2N, 20 // Microchimica Acta. 1984. Vol. 84. No. 5-6. pp. 389-397.
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TY - JOUR
DO - 10.1007/BF01197152
UR - http://link.springer.com/10.1007/BF01197152
TI - Solvent extraction of metals with macrocyclic compounds. I - The use of 15-membered compounds with donor system 2N, 20
T2 - Microchimica Acta
AU - Morosanova, E I
AU - Zolotov, Yu.A
AU - Bodnya, V A
AU - Formanovsky, A.A
PY - 1984
DA - 1984/09/01
PB - Springer Nature
SP - 389-397
IS - 5-6
VL - 84
SN - 0026-3672
SN - 1436-5073
ER -
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@article{1984_Morosanova,
author = {E I Morosanova and Yu.A Zolotov and V A Bodnya and A.A Formanovsky},
title = {Solvent extraction of metals with macrocyclic compounds. I - The use of 15-membered compounds with donor system 2N, 20},
journal = {Microchimica Acta},
year = {1984},
volume = {84},
publisher = {Springer Nature},
month = {sep},
url = {http://link.springer.com/10.1007/BF01197152},
number = {5-6},
pages = {389--397},
doi = {10.1007/BF01197152}
}
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MLA
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Morosanova, E. I., et al. “Solvent extraction of metals with macrocyclic compounds. I - The use of 15-membered compounds with donor system 2N, 20.” Microchimica Acta, vol. 84, no. 5-6, Sep. 1984, pp. 389-397. http://link.springer.com/10.1007/BF01197152.
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