Mechanism of the monomolecular thermal decomposition of tetrazole and 5-substituted tetrazoles
Publication type: Journal Article
Publication date: 1996-09-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The kinetic parameters of the thermal decomposition of tetrazole and 5-alkyl- and 5-aryl-substituted tetrazoles in melts of neat substances and in nitrobenzene solutions have been determined using the manometric method. The limiting stages of the monomolecular decomposition, which determine the observed rate of nitrogen formation, include the fast reversible transformation of the lH- and 2H-forms and the reversible opening of the 2H-form followed by the formation and subsequent cleavage of the corresponding intermediate diazo compound.
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12
Total citations:
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Citations from 2024:
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(8.33%)
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GOST
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Prokudin V. G., Poplavsky V. S., Ostrovskii V. A. Mechanism of the monomolecular thermal decomposition of tetrazole and 5-substituted tetrazoles // Russian Chemical Bulletin. 1996. Vol. 45. No. 9. pp. 2101-2104.
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Prokudin V. G., Poplavsky V. S., Ostrovskii V. A. Mechanism of the monomolecular thermal decomposition of tetrazole and 5-substituted tetrazoles // Russian Chemical Bulletin. 1996. Vol. 45. No. 9. pp. 2101-2104.
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RIS
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TY - JOUR
DO - 10.1007/bf01430718
UR - https://doi.org/10.1007/bf01430718
TI - Mechanism of the monomolecular thermal decomposition of tetrazole and 5-substituted tetrazoles
T2 - Russian Chemical Bulletin
AU - Prokudin, V G
AU - Poplavsky, V S
AU - Ostrovskii, V A
PY - 1996
DA - 1996/09/01
PB - Springer Nature
SP - 2101-2104
IS - 9
VL - 45
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{1996_Prokudin,
author = {V G Prokudin and V S Poplavsky and V A Ostrovskii},
title = {Mechanism of the monomolecular thermal decomposition of tetrazole and 5-substituted tetrazoles},
journal = {Russian Chemical Bulletin},
year = {1996},
volume = {45},
publisher = {Springer Nature},
month = {sep},
url = {https://doi.org/10.1007/bf01430718},
number = {9},
pages = {2101--2104},
doi = {10.1007/bf01430718}
}
Cite this
MLA
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Prokudin, V. G., et al. “Mechanism of the monomolecular thermal decomposition of tetrazole and 5-substituted tetrazoles.” Russian Chemical Bulletin, vol. 45, no. 9, Sep. 1996, pp. 2101-2104. https://doi.org/10.1007/bf01430718.