Tetramethyl(2-methylthioethyl)cyclopentadienyl complexes of zirconium(IV): Synthesis, crystal structure, and dynamic behavior in solutions
Publication type: Journal Article
Publication date: 1996-04-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Chelating sulfur-containing cyclopentadienyl ligand tetramethyl(2-methylthioethyl)cyclopentadiene (1), was synthesized for the first time. Its sodium (2a) and lithium (2b) derivatives were isolated in the crystalline state. Starting from compound1 some novel ZrIV complexes were prepared: [tetramethyl(2-methylthioethyl)cyclopentadienylltriclllorozirconium (3), bis[tetramethyl(2-methylthioethyl)cyclopentadienylldichlorozirconium (4), and [pentamethylcyclopentadienyll [tetramethyl(2-methylthioethyl)cyclopentadienylldichlorozirconium (5). The crystal structures of3 and5 were determined by X-ray diffraction analysis. The dynamic behavior of complex3 in various solvents was investigated by1H and13C N MR spectroscopy. The S→Zr coordination bond was shown to exist in complex3 both in the crystalline state and in solution. No coordination of this type was found in compounds4 and5.
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Krutko D. P. et al. Tetramethyl(2-methylthioethyl)cyclopentadienyl complexes of zirconium(IV): Synthesis, crystal structure, and dynamic behavior in solutions // Russian Chemical Bulletin. 1996. Vol. 45. No. 4. pp. 940-949.
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Krutko D. P., Borzov M. V., Petrosyan V. S., Kuz'mina L. G., Churakov A. Tetramethyl(2-methylthioethyl)cyclopentadienyl complexes of zirconium(IV): Synthesis, crystal structure, and dynamic behavior in solutions // Russian Chemical Bulletin. 1996. Vol. 45. No. 4. pp. 940-949.
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RIS
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TY - JOUR
DO - 10.1007/BF01431329
UR - http://link.springer.com/10.1007/BF01431329
TI - Tetramethyl(2-methylthioethyl)cyclopentadienyl complexes of zirconium(IV): Synthesis, crystal structure, and dynamic behavior in solutions
T2 - Russian Chemical Bulletin
AU - Krutko, D P
AU - Borzov, M V
AU - Petrosyan, V. S.
AU - Kuz'mina, L. G.
AU - Churakov, A.V.
PY - 1996
DA - 1996/04/01
PB - Springer Nature
SP - 940-949
IS - 4
VL - 45
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{1996_Krutko,
author = {D P Krutko and M V Borzov and V. S. Petrosyan and L. G. Kuz'mina and A.V. Churakov},
title = {Tetramethyl(2-methylthioethyl)cyclopentadienyl complexes of zirconium(IV): Synthesis, crystal structure, and dynamic behavior in solutions},
journal = {Russian Chemical Bulletin},
year = {1996},
volume = {45},
publisher = {Springer Nature},
month = {apr},
url = {http://link.springer.com/10.1007/BF01431329},
number = {4},
pages = {940--949},
doi = {10.1007/BF01431329}
}
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MLA
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Krutko, D. P., et al. “Tetramethyl(2-methylthioethyl)cyclopentadienyl complexes of zirconium(IV): Synthesis, crystal structure, and dynamic behavior in solutions.” Russian Chemical Bulletin, vol. 45, no. 4, Apr. 1996, pp. 940-949. http://link.springer.com/10.1007/BF01431329.