volume 45 issue 3 pages 564-572

Crown ether styryl dyes 17. Influence of the length of the N-substituent in betaines of chromogenic 15-crown-5-ethers on complexation with cations of alkaline-earth metals

Publication typeJournal Article
Publication date1996-03-01
scimago Q3
SJR0.305
CiteScore2.8
Impact factor
ISSN10665285, 15739171
General Chemistry
Abstract
The stoichiometry of complexation of crown ether styryl dyes with Mg2+, Ca2+, and Ba2+ ions and the dependence of the stability constants of these complexes on the length of theN-sulfoalkyl substituent were investigated. Introduction of a terminal sulfo group into theN-ethyl substituent had but a small effect on the stability constant for the complexes with 1 : I stoichiometry. Increase in the length of theN-substituent by one or two methylene groups resulted in a jumpwise rise of this constant. The effect observed was attributed to the formation of the intramolecular ion pair. The dimerization constant for Mg2+ complexes increased dramatically when passing from the sulfopropylN-substituent to the sulfobutyl one. The increase in the constant results from the decrease in steric strains in the dimeric complex.
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Stanislavskii O. B. et al. Crown ether styryl dyes 17. Influence of the length of the N-substituent in betaines of chromogenic 15-crown-5-ethers on complexation with cations of alkaline-earth metals // Russian Chemical Bulletin. 1996. Vol. 45. No. 3. pp. 564-572.
GOST all authors (up to 50) Copy
Stanislavskii O. B., Ushakov E. N., Gromov S. P., Fedorova O., Alfimov M. Crown ether styryl dyes 17. Influence of the length of the N-substituent in betaines of chromogenic 15-crown-5-ethers on complexation with cations of alkaline-earth metals // Russian Chemical Bulletin. 1996. Vol. 45. No. 3. pp. 564-572.
RIS |
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TY - JOUR
DO - 10.1007/BF01435783
UR - http://link.springer.com/10.1007/BF01435783
TI - Crown ether styryl dyes 17. Influence of the length of the N-substituent in betaines of chromogenic 15-crown-5-ethers on complexation with cations of alkaline-earth metals
T2 - Russian Chemical Bulletin
AU - Stanislavskii, O B
AU - Ushakov, E N
AU - Gromov, S P
AU - Fedorova, O.A.
AU - Alfimov, M.V.
PY - 1996
DA - 1996/03/01
PB - Springer Nature
SP - 564-572
IS - 3
VL - 45
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{1996_Stanislavskii,
author = {O B Stanislavskii and E N Ushakov and S P Gromov and O.A. Fedorova and M.V. Alfimov},
title = {Crown ether styryl dyes 17. Influence of the length of the N-substituent in betaines of chromogenic 15-crown-5-ethers on complexation with cations of alkaline-earth metals},
journal = {Russian Chemical Bulletin},
year = {1996},
volume = {45},
publisher = {Springer Nature},
month = {mar},
url = {http://link.springer.com/10.1007/BF01435783},
number = {3},
pages = {564--572},
doi = {10.1007/BF01435783}
}
MLA
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Stanislavskii, O. B., et al. “Crown ether styryl dyes 17. Influence of the length of the N-substituent in betaines of chromogenic 15-crown-5-ethers on complexation with cations of alkaline-earth metals.” Russian Chemical Bulletin, vol. 45, no. 3, Mar. 1996, pp. 564-572. http://link.springer.com/10.1007/BF01435783.
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