DSC and X-ray study of structure and phase transitions of low molecular compounds incorporated into crazes
Publication type: Journal Article
Publication date: 1992-05-01
scimago Q2
wos Q2
SJR: 0.551
CiteScore: 7.7
Impact factor: 3.1
ISSN: 13886150, 15882926, 03684466, 15728943, 14182874
Abstract
Orientation, phase composition and phase transitions of a series of long chain low molecular weight compounds (LMC), such as heneicosane, cetyl alcohol, normal fatty acids, introduced into porous structure (crazes) of polymeric matrices oriented in liquid medium have been studied by means of DSC and SAXS techniques. Different types of LMC crystallites orientation in crazes of polymeric matrices have been observed. LMC phase state in crazes is shown to be characterized by higher stability of high-temperature polymer midifications. LMC melting temperature in crazes usually decreases as well as melting enthalpy (heat) and entropy. The origin of LMC properties changes observed is high dispersity (40–100nm) of LMC particles in crazes resulting in a marked growth of polymer/LMC interface influence on principal thermodynamic parameters of the systems studied.
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Volkov A. et al. DSC and X-ray study of structure and phase transitions of low molecular compounds incorporated into crazes // Journal of Thermal Analysis and Calorimetry. 1992. Vol. 38. No. 5. pp. 1311-1322.
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Volkov A., Moscvina M. A., Arzhakova O. V., Volynskii A. L., Bakeev N. F. DSC and X-ray study of structure and phase transitions of low molecular compounds incorporated into crazes // Journal of Thermal Analysis and Calorimetry. 1992. Vol. 38. No. 5. pp. 1311-1322.
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TY - JOUR
DO - 10.1007/BF01979190
UR - http://link.springer.com/10.1007/BF01979190
TI - DSC and X-ray study of structure and phase transitions of low molecular compounds incorporated into crazes
T2 - Journal of Thermal Analysis and Calorimetry
AU - Volkov, A.V.
AU - Moscvina, M A
AU - Arzhakova, O V
AU - Volynskii, A L
AU - Bakeev, N F
PY - 1992
DA - 1992/05/01
PB - Springer Nature
SP - 1311-1322
IS - 5
VL - 38
SN - 1388-6150
SN - 1588-2926
SN - 0368-4466
SN - 1572-8943
SN - 1418-2874
ER -
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@article{1992_Volkov,
author = {A.V. Volkov and M A Moscvina and O V Arzhakova and A L Volynskii and N F Bakeev},
title = {DSC and X-ray study of structure and phase transitions of low molecular compounds incorporated into crazes},
journal = {Journal of Thermal Analysis and Calorimetry},
year = {1992},
volume = {38},
publisher = {Springer Nature},
month = {may},
url = {http://link.springer.com/10.1007/BF01979190},
number = {5},
pages = {1311--1322},
doi = {10.1007/BF01979190}
}
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Volkov, A.V., et al. “DSC and X-ray study of structure and phase transitions of low molecular compounds incorporated into crazes.” Journal of Thermal Analysis and Calorimetry, vol. 38, no. 5, May. 1992, pp. 1311-1322. http://link.springer.com/10.1007/BF01979190.
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