Extraction of palladium from nitrate solution by triphenylphosphine or triphenylphospine oxide in chloroform
Тип публикации: Journal Article
Дата публикации: 1992-04-01
scimago Q2
wos Q3
БС2
SJR: 0.388
CiteScore: 2.9
Impact factor: 1.6
ISSN: 02365731, 15882780
Spectroscopy
Analytical Chemistry
Health, Toxicology and Mutagenesis
Public Health, Environmental and Occupational Health
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Nuclear Energy and Engineering
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Краткое описание
It is found that from aqueous nitric acid media, Pd is highly extracted by chloroform solutions containing triphenylphosphine (Ph3P) and not extracted by triphenylphosphine oxide (Ph3PO) diluted with chloroform. The effect of diluent, nitric acid molarities, Ph3P concentration and temperature on palladium extraction by Ph3P was investigated. Slope analysis of the experimental results indicated that the main extracted species is in the form of Pd(NO3)2·2Ph3P.IR spectrum analysis of the extracted complex indicated the direct extraction of palladium as nitrate and bonding to phosphorus. Extraction of some fission product radionuclides from 2M HNO3 showed the selective extraction of palladium by Ph3P in chloroform.
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El-Reefy S., Daoud J. A., Aly H. Extraction of palladium from nitrate solution by triphenylphosphine or triphenylphospine oxide in chloroform // Journal of Radioanalytical and Nuclear Chemistry. 1992. Vol. 158. No. 2. pp. 303-312.
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El-Reefy S., Daoud J. A., Aly H. Extraction of palladium from nitrate solution by triphenylphosphine or triphenylphospine oxide in chloroform // Journal of Radioanalytical and Nuclear Chemistry. 1992. Vol. 158. No. 2. pp. 303-312.
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TY - JOUR
DO - 10.1007/bf02047117
UR - https://doi.org/10.1007/bf02047117
TI - Extraction of palladium from nitrate solution by triphenylphosphine or triphenylphospine oxide in chloroform
T2 - Journal of Radioanalytical and Nuclear Chemistry
AU - El-Reefy, S.A
AU - Daoud, J A
AU - Aly, H.F
PY - 1992
DA - 1992/04/01
PB - Springer Nature
SP - 303-312
IS - 2
VL - 158
SN - 0236-5731
SN - 1588-2780
ER -
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@article{1992_El-Reefy,
author = {S.A El-Reefy and J A Daoud and H.F Aly},
title = {Extraction of palladium from nitrate solution by triphenylphosphine or triphenylphospine oxide in chloroform},
journal = {Journal of Radioanalytical and Nuclear Chemistry},
year = {1992},
volume = {158},
publisher = {Springer Nature},
month = {apr},
url = {https://doi.org/10.1007/bf02047117},
number = {2},
pages = {303--312},
doi = {10.1007/bf02047117}
}
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El-Reefy, S.A, et al. “Extraction of palladium from nitrate solution by triphenylphosphine or triphenylphospine oxide in chloroform.” Journal of Radioanalytical and Nuclear Chemistry, vol. 158, no. 2, Apr. 1992, pp. 303-312. https://doi.org/10.1007/bf02047117.