Reactions of the radial cattions of acetic acid and acetic anhydride in CFCl3
Publication type: Journal Article
Publication date: 1985-11-01
scimago Q2
wos Q3
SJR: 0.388
CiteScore: 2.9
Impact factor: 1.6
ISSN: 02365731, 15882780
Spectroscopy
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Health, Toxicology and Mutagenesis
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Abstract
The ESR spectra of γ-irradiated, at −196 °C, solutions of acetic acid and acetic anhydride were studied depending on their concentrations in CFCl3. The structure of thus produced radical cations is confirmed with the deuterium substituted analogues. It has been shown that the ion-molecular reaction of the radical cation CH2COOH+ in the isolated dimer takes place for the dilute solutions of acetic acid in CFCl3 resulting in the formation of CH3COO follwed by its decomposition to CH3+CO2 while the radicals CH2COOH are formed via secondary processes. The reactions of radical cations of acetic oxide have been also studied.
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Belevskii V. N. et al. Reactions of the radial cattions of acetic acid and acetic anhydride in CFCl3 // Journal of Radioanalytical and Nuclear Chemistry. 1985. Vol. 96. No. 3. pp. 203-217.
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Belevskii V. N., Belopushkin S. I., Feldman V. I. Reactions of the radial cattions of acetic acid and acetic anhydride in CFCl3 // Journal of Radioanalytical and Nuclear Chemistry. 1985. Vol. 96. No. 3. pp. 203-217.
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RIS
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TY - JOUR
DO - 10.1007/BF02162579
UR - http://link.springer.com/10.1007/BF02162579
TI - Reactions of the radial cattions of acetic acid and acetic anhydride in CFCl3
T2 - Journal of Radioanalytical and Nuclear Chemistry
AU - Belevskii, V N
AU - Belopushkin, S I
AU - Feldman, V I
PY - 1985
DA - 1985/11/01
PB - Springer Nature
SP - 203-217
IS - 3
VL - 96
SN - 0236-5731
SN - 1588-2780
ER -
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BibTex (up to 50 authors)
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@article{1985_Belevskii,
author = {V N Belevskii and S I Belopushkin and V I Feldman},
title = {Reactions of the radial cattions of acetic acid and acetic anhydride in CFCl3},
journal = {Journal of Radioanalytical and Nuclear Chemistry},
year = {1985},
volume = {96},
publisher = {Springer Nature},
month = {nov},
url = {http://link.springer.com/10.1007/BF02162579},
number = {3},
pages = {203--217},
doi = {10.1007/BF02162579}
}
Cite this
MLA
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Belevskii, V. N., et al. “Reactions of the radial cattions of acetic acid and acetic anhydride in CFCl3.” Journal of Radioanalytical and Nuclear Chemistry, vol. 96, no. 3, Nov. 1985, pp. 203-217. http://link.springer.com/10.1007/BF02162579.