Reactions of the radical cations of aliphatic aldehydes in freon matrices
Publication type: Journal Article
Publication date: 1985-10-01
scimago Q2
wos Q3
SJR: 0.388
CiteScore: 2.9
Impact factor: 1.6
ISSN: 02365731, 15882780
Spectroscopy
Analytical Chemistry
Health, Toxicology and Mutagenesis
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Abstract
ESR spectra of γ-irradiated, at −196 °C, solutions of acetic and propionic aldehydes in freon-11 and freon-113 affected by aldehyde concentration, temperature, and the action of light have been studied. It has been shown that the radical cations CH3CHO+ are converted into neutral radicals CH3ĊO and CH3ĊHOH and the cations CH3CH2CHO+. are converted to RĊO and CH3ĊHCHO due to ion-molecular reactions of proton transfer /CH3ĊO and CH3ĊHCHO/ of hydrogen atom transfer /CH3ĊHOH/.
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Belevskii V. N. et al. Reactions of the radical cations of aliphatic aldehydes in freon matrices // Journal of Radioanalytical and Nuclear Chemistry. 1985. Vol. 96. No. 2. pp. 137-151.
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Belevskii V. N., Belopushkin S. I., Feldman V. I. Reactions of the radical cations of aliphatic aldehydes in freon matrices // Journal of Radioanalytical and Nuclear Chemistry. 1985. Vol. 96. No. 2. pp. 137-151.
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TY - JOUR
DO - 10.1007/BF02163080
UR - http://link.springer.com/10.1007/BF02163080
TI - Reactions of the radical cations of aliphatic aldehydes in freon matrices
T2 - Journal of Radioanalytical and Nuclear Chemistry
AU - Belevskii, V N
AU - Belopushkin, S I
AU - Feldman, V I
PY - 1985
DA - 1985/10/01
PB - Springer Nature
SP - 137-151
IS - 2
VL - 96
SN - 0236-5731
SN - 1588-2780
ER -
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BibTex (up to 50 authors)
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@article{1985_Belevskii,
author = {V N Belevskii and S I Belopushkin and V I Feldman},
title = {Reactions of the radical cations of aliphatic aldehydes in freon matrices},
journal = {Journal of Radioanalytical and Nuclear Chemistry},
year = {1985},
volume = {96},
publisher = {Springer Nature},
month = {oct},
url = {http://link.springer.com/10.1007/BF02163080},
number = {2},
pages = {137--151},
doi = {10.1007/BF02163080}
}
Cite this
MLA
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Belevskii, V. N., et al. “Reactions of the radical cations of aliphatic aldehydes in freon matrices.” Journal of Radioanalytical and Nuclear Chemistry, vol. 96, no. 2, Oct. 1985, pp. 137-151. http://link.springer.com/10.1007/BF02163080.