Journal of Radioanalytical and Nuclear Chemistry

, том 96 , издание 2 , страницы 137-151

Reactions of the radical cations of aliphatic aldehydes in freon matrices

Тип публикации: Journal Article

Дата публикации: 1985-10-01

Springer Nature

Journal of Radioanalytical and Nuclear Chemistry

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SJR: 0.388

CiteScore: 2.9

Impact factor: 1.6

ISSN: 02365731, 15882780

DOI: 10.1007/BF02163080

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Spectroscopy

Analytical Chemistry

Health, Toxicology and Mutagenesis

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ESR spectra of γ-irradiated, at −196 °C, solutions of acetic and propionic aldehydes in freon-11 and freon-113 affected by aldehyde concentration, temperature, and the action of light have been studied. It has been shown that the radical cations CH3CHO+ are converted into neutral radicals CH3ĊO and CH3ĊHOH and the cations CH3CH2CHO+. are converted to RĊO and CH3ĊHCHO due to ion-molecular reactions of proton transfer /CH3ĊO and CH3ĊHCHO/ of hydrogen atom transfer /CH3ĊHOH/.

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Astrophysical Journal	Astrophysical Journal, 1, 11.11% Astrophysical Journal 1 публикация, 11.11%
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Belevskii V. N. et al. Reactions of the radical cations of aliphatic aldehydes in freon matrices // Journal of Radioanalytical and Nuclear Chemistry. 1985. Vol. 96. No. 2. pp. 137-151.

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Belevskii V. N., Belopushkin S. I., Feldman V. I. Reactions of the radical cations of aliphatic aldehydes in freon matrices // Journal of Radioanalytical and Nuclear Chemistry. 1985. Vol. 96. No. 2. pp. 137-151.

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TY - JOUR

DO - 10.1007/BF02163080

UR - http://link.springer.com/10.1007/BF02163080

TI - Reactions of the radical cations of aliphatic aldehydes in freon matrices

T2 - Journal of Radioanalytical and Nuclear Chemistry

AU - Belevskii, V N

AU - Belopushkin, S I

AU - Feldman, V I

PY - 1985

DA - 1985/10/01

PB - Springer Nature

SP - 137-151

IS - 2

VL - 96

SN - 0236-5731

SN - 1588-2780

ER -

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@article{1985_Belevskii,

author = {V N Belevskii and S I Belopushkin and V I Feldman},

title = {Reactions of the radical cations of aliphatic aldehydes in freon matrices},

journal = {Journal of Radioanalytical and Nuclear Chemistry},

year = {1985},

volume = {96},

publisher = {Springer Nature},

month = {oct},

url = {http://link.springer.com/10.1007/BF02163080},

number = {2},

pages = {137--151},

doi = {10.1007/BF02163080}

}

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Belevskii, V. N., et al. “Reactions of the radical cations of aliphatic aldehydes in freon matrices.” Journal of Radioanalytical and Nuclear Chemistry, vol. 96, no. 2, Oct. 1985, pp. 137-151. http://link.springer.com/10.1007/BF02163080.