Journal of Radioanalytical and Nuclear Chemistry

, том 107 , издание 3 , страницы 129-146

Formation of radicals in the liquid and solid-phase radiolysis of esters studied by spin trapping

V N Belevsky ¹

S I Belopushkin ¹

V I Feldman ¹

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Department of Chemistry, Moscow State University, Moscow, USSR | |

Тип публикации: Journal Article

Дата публикации: 1986-11-01

Springer Nature

Journal of Radioanalytical and Nuclear Chemistry

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SJR: 0.388

CiteScore: 2.9

Impact factor: 1.6

ISSN: 02365731, 15882780

DOI: 10.1007/BF02163398

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Spectroscopy

Analytical Chemistry

Health, Toxicology and Mutagenesis

Public Health, Environmental and Occupational Health

Pollution

Radiology Nuclear Medicine and imaging

Nuclear Energy and Engineering

Краткое описание

The radiolysis of some esters /formates and acetates/ has been studied both in liquid and in solid states using a number of different spin traps. Specific deuteration was applied to elucidate the mechanism of radical formation. The radicals were found to result from the reactions of ester radical cations, radical anions and excited molecules. Evidence for intramolecular rearrangement in the radical cations of esters in condensed phase was obtained.

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Radiation Physics and Chemistry	Radiation Physics and Chemistry, 1, 6.25% Radiation Physics and Chemistry 1 публикация, 6.25%
Magnetic Resonance in Chemistry	Magnetic Resonance in Chemistry, 1, 6.25% Magnetic Resonance in Chemistry 1 публикация, 6.25%
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Belevsky V. N. et al. Formation of radicals in the liquid and solid-phase radiolysis of esters studied by spin trapping // Journal of Radioanalytical and Nuclear Chemistry. 1986. Vol. 107. No. 3. pp. 129-146.

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Belevsky V. N., Belopushkin S. I., Feldman V. I. Formation of radicals in the liquid and solid-phase radiolysis of esters studied by spin trapping // Journal of Radioanalytical and Nuclear Chemistry. 1986. Vol. 107. No. 3. pp. 129-146.

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TY - JOUR

DO - 10.1007/BF02163398

UR - http://link.springer.com/10.1007/BF02163398

TI - Formation of radicals in the liquid and solid-phase radiolysis of esters studied by spin trapping

T2 - Journal of Radioanalytical and Nuclear Chemistry

AU - Belevsky, V N

AU - Belopushkin, S I

AU - Feldman, V I

PY - 1986

DA - 1986/11/01

PB - Springer Nature

SP - 129-146

IS - 3

VL - 107

SN - 0236-5731

SN - 1588-2780

ER -

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@article{1986_Belevsky,

author = {V N Belevsky and S I Belopushkin and V I Feldman},

title = {Formation of radicals in the liquid and solid-phase radiolysis of esters studied by spin trapping},

journal = {Journal of Radioanalytical and Nuclear Chemistry},

year = {1986},

volume = {107},

publisher = {Springer Nature},

month = {nov},

url = {http://link.springer.com/10.1007/BF02163398},

number = {3},

pages = {129--146},

doi = {10.1007/BF02163398}

}

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Belevsky, V. N., et al. “Formation of radicals in the liquid and solid-phase radiolysis of esters studied by spin trapping.” Journal of Radioanalytical and Nuclear Chemistry, vol. 107, no. 3, Nov. 1986, pp. 129-146. http://link.springer.com/10.1007/BF02163398.