Journal of Radioanalytical and Nuclear Chemistry

, том 107 , издание 2 , страницы 81-93

Formation and reactions of monomeric and dimeric radical cations of aliphatic ketones in freon matrices

Тип публикации: Journal Article

Дата публикации: 1986-11-01

Springer Nature

Journal of Radioanalytical and Nuclear Chemistry

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SJR: 0.388

CiteScore: 2.9

Impact factor: 1.6

ISSN: 02365731, 15882780

DOI: 10.1007/BF02163444

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Spectroscopy

Analytical Chemistry

Health, Toxicology and Mutagenesis

Public Health, Environmental and Occupational Health

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Краткое описание

ESR spectra of γ-irradiated, at 77 K, acetone and CH3COEt solutions /0.1–22%/ in CFCl3 were studied. The yields of monomer and dimer radical cations of ketones and RCHCOCH3 radicals depend on ketone concentration in CFCl3. When exposed to light the dimeric radical cations are transformed into RCHCOMe, while the monomeric radical cations disappear without further radical production. Different types of solid phase ion-molecular reaction for monomer and dimer radical cations are discussed.

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Belevsky V. N. et al. Formation and reactions of monomeric and dimeric radical cations of aliphatic ketones in freon matrices // Journal of Radioanalytical and Nuclear Chemistry. 1986. Vol. 107. No. 2. pp. 81-93.

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Belevsky V. N., Belopushkin S. I., Feldman V. I. Formation and reactions of monomeric and dimeric radical cations of aliphatic ketones in freon matrices // Journal of Radioanalytical and Nuclear Chemistry. 1986. Vol. 107. No. 2. pp. 81-93.

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TY - JOUR

DO - 10.1007/BF02163444

UR - http://link.springer.com/10.1007/BF02163444

TI - Formation and reactions of monomeric and dimeric radical cations of aliphatic ketones in freon matrices

T2 - Journal of Radioanalytical and Nuclear Chemistry

AU - Belevsky, V N

AU - Belopushkin, S I

AU - Feldman, V I

PY - 1986

DA - 1986/11/01

PB - Springer Nature

SP - 81-93

IS - 2

VL - 107

SN - 0236-5731

SN - 1588-2780

ER -

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@article{1986_Belevsky,

author = {V N Belevsky and S I Belopushkin and V I Feldman},

title = {Formation and reactions of monomeric and dimeric radical cations of aliphatic ketones in freon matrices},

journal = {Journal of Radioanalytical and Nuclear Chemistry},

year = {1986},

volume = {107},

publisher = {Springer Nature},

month = {nov},

url = {http://link.springer.com/10.1007/BF02163444},

number = {2},

pages = {81--93},

doi = {10.1007/BF02163444}

}

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Belevsky, V. N., et al. “Formation and reactions of monomeric and dimeric radical cations of aliphatic ketones in freon matrices.” Journal of Radioanalytical and Nuclear Chemistry, vol. 107, no. 2, Nov. 1986, pp. 81-93. http://link.springer.com/10.1007/BF02163444.