Formation and reactions of monomeric and dimeric radical cations of aliphatic ketones in freon matrices
Publication type: Journal Article
Publication date: 1986-11-01
scimago Q2
wos Q3
SJR: 0.388
CiteScore: 2.9
Impact factor: 1.6
ISSN: 02365731, 15882780
Spectroscopy
Analytical Chemistry
Health, Toxicology and Mutagenesis
Public Health, Environmental and Occupational Health
Pollution
Radiology Nuclear Medicine and imaging
Nuclear Energy and Engineering
Abstract
ESR spectra of γ-irradiated, at 77 K, acetone and CH3COEt solutions /0.1–22%/ in CFCl3 were studied. The yields of monomer and dimer radical cations of ketones and RCHCOCH3 radicals depend on ketone concentration in CFCl3. When exposed to light the dimeric radical cations are transformed into RCHCOMe, while the monomeric radical cations disappear without further radical production. Different types of solid phase ion-molecular reaction for monomer and dimer radical cations are discussed.
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Belevsky V. N. et al. Formation and reactions of monomeric and dimeric radical cations of aliphatic ketones in freon matrices // Journal of Radioanalytical and Nuclear Chemistry. 1986. Vol. 107. No. 2. pp. 81-93.
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Belevsky V. N., Belopushkin S. I., Feldman V. I. Formation and reactions of monomeric and dimeric radical cations of aliphatic ketones in freon matrices // Journal of Radioanalytical and Nuclear Chemistry. 1986. Vol. 107. No. 2. pp. 81-93.
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RIS
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TY - JOUR
DO - 10.1007/BF02163444
UR - http://link.springer.com/10.1007/BF02163444
TI - Formation and reactions of monomeric and dimeric radical cations of aliphatic ketones in freon matrices
T2 - Journal of Radioanalytical and Nuclear Chemistry
AU - Belevsky, V N
AU - Belopushkin, S I
AU - Feldman, V I
PY - 1986
DA - 1986/11/01
PB - Springer Nature
SP - 81-93
IS - 2
VL - 107
SN - 0236-5731
SN - 1588-2780
ER -
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BibTex (up to 50 authors)
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@article{1986_Belevsky,
author = {V N Belevsky and S I Belopushkin and V I Feldman},
title = {Formation and reactions of monomeric and dimeric radical cations of aliphatic ketones in freon matrices},
journal = {Journal of Radioanalytical and Nuclear Chemistry},
year = {1986},
volume = {107},
publisher = {Springer Nature},
month = {nov},
url = {http://link.springer.com/10.1007/BF02163444},
number = {2},
pages = {81--93},
doi = {10.1007/BF02163444}
}
Cite this
MLA
Copy
Belevsky, V. N., et al. “Formation and reactions of monomeric and dimeric radical cations of aliphatic ketones in freon matrices.” Journal of Radioanalytical and Nuclear Chemistry, vol. 107, no. 2, Nov. 1986, pp. 81-93. http://link.springer.com/10.1007/BF02163444.