Reactions of radical cations of acetals: Evidence for unimolecular decomposition
Publication type: Journal Article
Publication date: 1988-01-01
scimago Q2
wos Q3
SJR: 0.388
CiteScore: 2.9
Impact factor: 1.6
ISSN: 02365731, 15882780
Spectroscopy
Analytical Chemistry
Health, Toxicology and Mutagenesis
Public Health, Environmental and Occupational Health
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Abstract
The thermal and photochemical reactions of the methylal radical cation /I/ in freon matrices were studied using selective deuteration for elucidating the structure of the resulting species. /I/ has been shown to decay by unimolecular reaction upon heating to 140 K as well as upon photolysis in CFCl3 matrix and the product of decay has been assumed to be the complex of formaldehyde radical cation with CFCl3. Such decay reaction has been demonstrated for 1,3-dioxolan radical cation as well.
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9
Total citations:
9
Citations from 2024:
1
(11%)
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GOST
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Baranova I. A. et al. Reactions of radical cations of acetals: Evidence for unimolecular decomposition // Journal of Radioanalytical and Nuclear Chemistry. 1988. Vol. 126. No. 1. pp. 39-51.
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Baranova I. A., Feldman V. I., Belevskii V. N. Reactions of radical cations of acetals: Evidence for unimolecular decomposition // Journal of Radioanalytical and Nuclear Chemistry. 1988. Vol. 126. No. 1. pp. 39-51.
Cite this
RIS
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TY - JOUR
DO - 10.1007/BF02164802
UR - http://link.springer.com/10.1007/BF02164802
TI - Reactions of radical cations of acetals: Evidence for unimolecular decomposition
T2 - Journal of Radioanalytical and Nuclear Chemistry
AU - Baranova, I A
AU - Feldman, V I
AU - Belevskii, V N
PY - 1988
DA - 1988/01/01
PB - Springer Nature
SP - 39-51
IS - 1
VL - 126
SN - 0236-5731
SN - 1588-2780
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1988_Baranova,
author = {I A Baranova and V I Feldman and V N Belevskii},
title = {Reactions of radical cations of acetals: Evidence for unimolecular decomposition},
journal = {Journal of Radioanalytical and Nuclear Chemistry},
year = {1988},
volume = {126},
publisher = {Springer Nature},
month = {jan},
url = {http://link.springer.com/10.1007/BF02164802},
number = {1},
pages = {39--51},
doi = {10.1007/BF02164802}
}
Cite this
MLA
Copy
Baranova, I. A., et al. “Reactions of radical cations of acetals: Evidence for unimolecular decomposition.” Journal of Radioanalytical and Nuclear Chemistry, vol. 126, no. 1, Jan. 1988, pp. 39-51. http://link.springer.com/10.1007/BF02164802.