Journal of Radioanalytical and Nuclear Chemistry

, том 126 , издание 1 , страницы 39-51

Reactions of radical cations of acetals: Evidence for unimolecular decomposition

Тип публикации: Journal Article

Дата публикации: 1988-01-01

Springer Nature

Journal of Radioanalytical and Nuclear Chemistry

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SJR: 0.388

CiteScore: 2.9

Impact factor: 1.6

ISSN: 02365731, 15882780

DOI: 10.1007/BF02164802

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Краткое описание

The thermal and photochemical reactions of the methylal radical cation /I/ in freon matrices were studied using selective deuteration for elucidating the structure of the resulting species. /I/ has been shown to decay by unimolecular reaction upon heating to 140 K as well as upon photolysis in CFCl3 matrix and the product of decay has been assumed to be the complex of formaldehyde radical cation with CFCl3. Such decay reaction has been demonstrated for 1,3-dioxolan radical cation as well.

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Baranova I. A. et al. Reactions of radical cations of acetals: Evidence for unimolecular decomposition // Journal of Radioanalytical and Nuclear Chemistry. 1988. Vol. 126. No. 1. pp. 39-51.

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Baranova I. A., Feldman V. I., Belevskii V. N. Reactions of radical cations of acetals: Evidence for unimolecular decomposition // Journal of Radioanalytical and Nuclear Chemistry. 1988. Vol. 126. No. 1. pp. 39-51.

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TY - JOUR

DO - 10.1007/BF02164802

UR - http://link.springer.com/10.1007/BF02164802

TI - Reactions of radical cations of acetals: Evidence for unimolecular decomposition

T2 - Journal of Radioanalytical and Nuclear Chemistry

AU - Baranova, I A

AU - Feldman, V I

AU - Belevskii, V N

PY - 1988

DA - 1988/01/01

PB - Springer Nature

SP - 39-51

IS - 1

VL - 126

SN - 0236-5731

SN - 1588-2780

ER -

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@article{1988_Baranova,

author = {I A Baranova and V I Feldman and V N Belevskii},

title = {Reactions of radical cations of acetals: Evidence for unimolecular decomposition},

journal = {Journal of Radioanalytical and Nuclear Chemistry},

year = {1988},

volume = {126},

publisher = {Springer Nature},

month = {jan},

url = {http://link.springer.com/10.1007/BF02164802},

number = {1},

pages = {39--51},

doi = {10.1007/BF02164802}

}

MLA

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Baranova, I. A., et al. “Reactions of radical cations of acetals: Evidence for unimolecular decomposition.” Journal of Radioanalytical and Nuclear Chemistry, vol. 126, no. 1, Jan. 1988, pp. 39-51. http://link.springer.com/10.1007/BF02164802.