Influence of heteroatom nature on the paths of formation of intermediates in gamma-irradiated cyclic ethers at 77 K
Тип публикации: Journal Article
Дата публикации: 1998-04-01
SCImago Q3
WOS Q3
БС2
SJR: 0.354
CiteScore: 2.7
Impact factor: 1.7
ISSN: 02365731, 15882780
Spectroscopy
Analytical Chemistry
Health, Toxicology and Mutagenesis
Public Health, Environmental and Occupational Health
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Radiology Nuclear Medicine and imaging
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Краткое описание
Gamma-irradiated at 77 K 1,4-dioxane and morpholine have been studied by ESR-spectroscopy. C-O bond dissociation is the main process in the γ-radiolysis of 1,4-dioxane and a significant contribution of −CH−CH=O radicals to the experimental spectrum is observed. Both H-atom abstraction and the cleavage of the ring seems to occur at low temperature γ-radiolysis of morpholine. The paths of formation of intermediates in cyclic ethers γ-irradiated at 77 K are discussed.
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Nesterov S. Influence of heteroatom nature on the paths of formation of intermediates in gamma-irradiated cyclic ethers at 77 K // Journal of Radioanalytical and Nuclear Chemistry. 1998. Vol. 230. No. 1-2. pp. 273-276.
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Nesterov S. Influence of heteroatom nature on the paths of formation of intermediates in gamma-irradiated cyclic ethers at 77 K // Journal of Radioanalytical and Nuclear Chemistry. 1998. Vol. 230. No. 1-2. pp. 273-276.
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TY - JOUR
DO - 10.1007/BF02387478
UR - http://link.springer.com/10.1007/BF02387478
TI - Influence of heteroatom nature on the paths of formation of intermediates in gamma-irradiated cyclic ethers at 77 K
T2 - Journal of Radioanalytical and Nuclear Chemistry
AU - Nesterov, S.V.
PY - 1998
DA - 1998/04/01
PB - Springer Nature
SP - 273-276
IS - 1-2
VL - 230
SN - 0236-5731
SN - 1588-2780
ER -
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@article{1998_Nesterov,
author = {S.V. Nesterov},
title = {Influence of heteroatom nature on the paths of formation of intermediates in gamma-irradiated cyclic ethers at 77 K},
journal = {Journal of Radioanalytical and Nuclear Chemistry},
year = {1998},
volume = {230},
publisher = {Springer Nature},
month = {apr},
url = {http://link.springer.com/10.1007/BF02387478},
number = {1-2},
pages = {273--276},
doi = {10.1007/BF02387478}
}
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Nesterov, S.V.. “Influence of heteroatom nature on the paths of formation of intermediates in gamma-irradiated cyclic ethers at 77 K.” Journal of Radioanalytical and Nuclear Chemistry, vol. 230, no. 1-2, Apr. 1998, pp. 273-276. http://link.springer.com/10.1007/BF02387478.
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