Springer Nature
Reaction Kinetics and Catalysis Letters
,  том 66 ,  издание 1 ,  страницы 163-168

Fast reactions of*CH2(CH3)NCHO radicals from the photolysis of Feaq 3+ in the presence ofN,N-dimethylformamide

Тип публикации: Journal Article
Дата публикации: 1999-01-01
Springer Nature
SJR: —
CiteScore: —
Impact factor: —
ISSN: 01331736, 15882837
Catalysis
Physical and Theoretical Chemistry
Краткое описание
Laser flash photolysis was used to study the photochemistry of Feaq 3+ complex in aqueous solutions with additions ofN,N-dimethylformamide. An electronic absorption band with a maximum at 380 nm belonging to the*CH2(CH3)NCHO radical was recorded. The recombination (or disproportionation) rate constants of*CH2(CH3)NCHO radicals and their reaction with the Feaq 3+ complex were estimated to be (3.4±0.8)×109 M−1s−1 and (4.3±0.6)×107 M−1s−1, respectively. The mechanism of radical formation is discussed.
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Ivanov K. et al. Fast reactions of*CH2(CH3)NCHO radicals from the photolysis of Feaq 3+ in the presence ofN,N-dimethylformamide // Reaction Kinetics and Catalysis Letters. 1999. Vol. 66. No. 1. pp. 163-168.
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Ivanov K., Glebov E., Plyusnin V. F., Ivanov Y. V., Grivin V. P., Bazhin N. M. Fast reactions of*CH2(CH3)NCHO radicals from the photolysis of Feaq 3+ in the presence ofN,N-dimethylformamide // Reaction Kinetics and Catalysis Letters. 1999. Vol. 66. No. 1. pp. 163-168.
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TY - JOUR
DO - 10.1007/bf02475756
UR - https://doi.org/10.1007/bf02475756
TI - Fast reactions of*CH2(CH3)NCHO radicals from the photolysis of Feaq 3+ in the presence ofN,N-dimethylformamide
T2 - Reaction Kinetics and Catalysis Letters
AU - Ivanov, K.L
AU - Glebov, E.M
AU - Plyusnin, V F
AU - Ivanov, Yu. V.
AU - Grivin, V P
AU - Bazhin, N. M.
PY - 1999
DA - 1999/01/01
PB - Springer Nature
SP - 163-168
IS - 1
VL - 66
SN - 0133-1736
SN - 1588-2837
ER -
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@article{1999_Ivanov,
author = {K.L Ivanov and E.M Glebov and V F Plyusnin and Yu. V. Ivanov and V P Grivin and N. M. Bazhin},
title = {Fast reactions of*CH2(CH3)NCHO radicals from the photolysis of Feaq 3+ in the presence ofN,N-dimethylformamide},
journal = {Reaction Kinetics and Catalysis Letters},
year = {1999},
volume = {66},
publisher = {Springer Nature},
month = {jan},
url = {https://doi.org/10.1007/bf02475756},
number = {1},
pages = {163--168},
doi = {10.1007/bf02475756}
}
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Ivanov, K.L, et al. “Fast reactions of*CH2(CH3)NCHO radicals from the photolysis of Feaq 3+ in the presence ofN,N-dimethylformamide.” Reaction Kinetics and Catalysis Letters, vol. 66, no. 1, Jan. 1999, pp. 163-168. https://doi.org/10.1007/bf02475756.