Electrochemical oxidation of malonic esters in acetonitrile in the presence of iodides as mediators
Publication type: Journal Article
Publication date: 1997-03-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Electrochemical oxidation of malonic esters in acetonitrile in the presence of iodides follows two different pathways depending on the nature of the cation. In the presence of Lil, alkyl 1,1,2,2,3,3-propanetetracarboxylates were obtained in 85–98% yields. In the presence of Nal, Kl, or Bu4NI, the formation of 1,1,2,2-ethanetetracarboxylates and their subsequent dehydrogenation to ethenetetracarboxylates was the main reaction pathway.
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Fedukovich S. K., Elinson M. N., Nikishin G. I. Electrochemical oxidation of malonic esters in acetonitrile in the presence of iodides as mediators // Russian Chemical Bulletin. 1997. Vol. 46. No. 3. pp. 599-602.
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Fedukovich S. K., Elinson M. N., Nikishin G. I. Electrochemical oxidation of malonic esters in acetonitrile in the presence of iodides as mediators // Russian Chemical Bulletin. 1997. Vol. 46. No. 3. pp. 599-602.
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TY - JOUR
DO - 10.1007/BF02495426
UR - https://doi.org/10.1007/BF02495426
TI - Electrochemical oxidation of malonic esters in acetonitrile in the presence of iodides as mediators
T2 - Russian Chemical Bulletin
AU - Fedukovich, S K
AU - Elinson, M. N.
AU - Nikishin, G. I.
PY - 1997
DA - 1997/03/01
PB - Springer Nature
SP - 599-602
IS - 3
VL - 46
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{1997_Fedukovich,
author = {S K Fedukovich and M. N. Elinson and G. I. Nikishin},
title = {Electrochemical oxidation of malonic esters in acetonitrile in the presence of iodides as mediators},
journal = {Russian Chemical Bulletin},
year = {1997},
volume = {46},
publisher = {Springer Nature},
month = {mar},
url = {https://doi.org/10.1007/BF02495426},
number = {3},
pages = {599--602},
doi = {10.1007/BF02495426}
}
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MLA
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Fedukovich, S. K., et al. “Electrochemical oxidation of malonic esters in acetonitrile in the presence of iodides as mediators.” Russian Chemical Bulletin, vol. 46, no. 3, Mar. 1997, pp. 599-602. https://doi.org/10.1007/BF02495426.