Microchimica Acta, volume 186, issue 3, publication number 188
Dynamic gas extraction of iodine in combination with a silver triangular nanoplate-modified paper strip for colorimetric determination of iodine and of iodine-interacting compounds
Gorbunova Marina O
1, 2
,
Baulina Anastasiya A
1
,
Kulyaginova Margarita S
2
,
Apyari Vladimir
3
,
Volkov Pavel A.
4
,
Bochenkov Vladimir E
3
,
Starukhin Aleksandr S
5
,
4
Publication type: Journal Article
Publication date: 2019-02-15
Journal:
Microchimica Acta
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.7
ISSN: 00263672, 14365073
Analytical Chemistry
Abstract
AbstractA method is described for sensitive and selective detection of iodine by using a paper strip modified with silver triangular nanoplates (AgTNPs). It is based on the extraction of iodine from a solution into a flow of air via dynamic gas extraction and transferring it through a reactive paper modified with AgTNPs. The interaction of AgTNPs with iodine results in a color change from blue to white. This can be visually detected and monitored by digital colorimetry. The dynamic gas extraction is highly selective for volatile compounds so that a sample pretreatment is minimal. Due to the sensitivity of AgTNPs for iodine, the limit of its detection is as low as 7 μg L−1, and the analytical range is of 20–200 μg L−1. The method also was applied in a new approach for determination of organic compounds that can interact with iodine. The organic compound is exposed to an excess of iodine, and this is followed by detection of residual iodine as described above. The method was applied to the determination of ascorbic acid, caffeine and the drug metamizole.
Graphical abstractSchematic representation of a procedure of organic iodine-interacting compounds (Org.) determination. It is based on their iodination followed by gas extraction of the residual iodine, its interaction with silver triangular nanoplates and colorimetric detection with a scanner.
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- Statistics recalculated weekly.
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Gorbunova M. O. et al. Dynamic gas extraction of iodine in combination with a silver triangular nanoplate-modified paper strip for colorimetric determination of iodine and of iodine-interacting compounds // Microchimica Acta. 2019. Vol. 186. No. 3. 188
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Gorbunova M. O., Baulina A. A., Kulyaginova M. S., Apyari V., Furletov A. A., Volkov P. A., Bochenkov V. E., Starukhin A. S., Dmitrienko S. G. Dynamic gas extraction of iodine in combination with a silver triangular nanoplate-modified paper strip for colorimetric determination of iodine and of iodine-interacting compounds // Microchimica Acta. 2019. Vol. 186. No. 3. 188
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TY - JOUR
DO - 10.1007/S00604-019-3300-5
UR - https://doi.org/10.1007%2FS00604-019-3300-5
TI - Dynamic gas extraction of iodine in combination with a silver triangular nanoplate-modified paper strip for colorimetric determination of iodine and of iodine-interacting compounds
T2 - Microchimica Acta
AU - Baulina, Anastasiya A
AU - Kulyaginova, Margarita S
AU - Apyari, Vladimir
AU - Furletov, Aleksei A
AU - Volkov, Pavel A.
AU - Starukhin, Aleksandr S
AU - Gorbunova, Marina O
AU - Bochenkov, Vladimir E
AU - Dmitrienko, Stanislava G
PY - 2019
DA - 2019/02/15 00:00:00
PB - Springer Nature
IS - 3
VL - 186
SN - 0026-3672
SN - 1436-5073
ER -
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@article{2019_Gorbunova
author = {Anastasiya A Baulina and Margarita S Kulyaginova and Vladimir Apyari and Aleksei A Furletov and Pavel A. Volkov and Aleksandr S Starukhin and Marina O Gorbunova and Vladimir E Bochenkov and Stanislava G Dmitrienko},
title = {Dynamic gas extraction of iodine in combination with a silver triangular nanoplate-modified paper strip for colorimetric determination of iodine and of iodine-interacting compounds},
journal = {Microchimica Acta},
year = {2019},
volume = {186},
publisher = {Springer Nature},
month = {feb},
url = {https://doi.org/10.1007%2FS00604-019-3300-5},
number = {3},
doi = {10.1007/S00604-019-3300-5}
}