Radiolysis of aqueous DCH18C6 solutions at 77 K
Тип публикации: Journal Article
Дата публикации: 2008-09-27
scimago Q2
wos Q3
БС2
SJR: 0.388
CiteScore: 2.9
Impact factor: 1.6
ISSN: 02365731, 15882780
Spectroscopy
Analytical Chemistry
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Краткое описание
Low-temperature (77 K) γ- and X-ray radiolysis of aqueous DCH18C6 solutions was studied by ESR-spectroscopy. OH radicals, trapped electrons and macrocyclic radicals -CH2-CH-O- resulting from H-atom abstraction from methylene groups of polyether ring were identified as predominant radiolysis products. Increasing the crown ether concentration in aqueous solution leads to the growth of relative yields of the trapped electron and macrocyclic radicals as well as the decrease of that of hydroxyl radical. Neither radical products of macrocycle rupture nor H-atom abstraction from cyclohexane rings were observed.
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Zakurdaeva O. A. et al. Radiolysis of aqueous DCH18C6 solutions at 77 K // Journal of Radioanalytical and Nuclear Chemistry. 2008. Vol. 279. No. 2. pp. 647-653.
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Zakurdaeva O. A., Nesterov S., Feldman V. I. Radiolysis of aqueous DCH18C6 solutions at 77 K // Journal of Radioanalytical and Nuclear Chemistry. 2008. Vol. 279. No. 2. pp. 647-653.
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TY - JOUR
DO - 10.1007/S10967-008-7345-X
UR - http://link.springer.com/10.1007/s10967-008-7345-x
TI - Radiolysis of aqueous DCH18C6 solutions at 77 K
T2 - Journal of Radioanalytical and Nuclear Chemistry
AU - Zakurdaeva, O A
AU - Nesterov, S.V.
AU - Feldman, V I
PY - 2008
DA - 2008/09/27
PB - Springer Nature
SP - 647-653
IS - 2
VL - 279
SN - 0236-5731
SN - 1588-2780
ER -
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@article{2008_Zakurdaeva,
author = {O A Zakurdaeva and S.V. Nesterov and V I Feldman},
title = {Radiolysis of aqueous DCH18C6 solutions at 77 K},
journal = {Journal of Radioanalytical and Nuclear Chemistry},
year = {2008},
volume = {279},
publisher = {Springer Nature},
month = {sep},
url = {http://link.springer.com/10.1007/s10967-008-7345-x},
number = {2},
pages = {647--653},
doi = {10.1007/S10967-008-7345-X}
}
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Zakurdaeva, O. A., et al. “Radiolysis of aqueous DCH18C6 solutions at 77 K.” Journal of Radioanalytical and Nuclear Chemistry, vol. 279, no. 2, Sep. 2008, pp. 647-653. http://link.springer.com/10.1007/s10967-008-7345-x.
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