Influence of valence environment on the O?Si bond in pentacoordinated silicon compounds. 2. Crystal structure of three O?Si trifluorosilanes
Publication type: Journal Article
Publication date: 1994-01-01
scimago Q4
wos Q4
SJR: 0.211
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00224766, 15738779
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
We have determined crystal structures of three pentacoordinated silicon compounds: 3-(trifluorosilyl)-2-cyanoethylpropionate (I), N-methyl-N-(trifluorosilylmethyl)acetamide (II), and N-methyl-N-(trifluorosilylmethyl)trifluoroacetamide (III). The coordination O→Si bond length is 2.729 and 2.668(5) in I (for two independent molecules), 1.879(1) in II, and 1.942(2) Å in III. We concluded that mutual orientation of the carboxyl group and the =O→Si bond has a strong effect on the length of the latter. In the molecular packing of I, there is a structural motif of rows of close-packed SiF3 fragments.
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Ovchinnikov Y. E. et al. Influence of valence environment on the O?Si bond in pentacoordinated silicon compounds. 2. Crystal structure of three O?Si trifluorosilanes // Journal of Structural Chemistry. 1994. Vol. 34. No. 6. pp. 888-894.
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Ovchinnikov Y. E., Mozzhukhin A. O., Antipin M. Y., Struchkov Y. T., Baryshok V. P., Lazareva N. F., Voronkov M. G. Influence of valence environment on the O?Si bond in pentacoordinated silicon compounds. 2. Crystal structure of three O?Si trifluorosilanes // Journal of Structural Chemistry. 1994. Vol. 34. No. 6. pp. 888-894.
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TY - JOUR
DO - 10.1007/bf00752862
UR - https://doi.org/10.1007/bf00752862
TI - Influence of valence environment on the O?Si bond in pentacoordinated silicon compounds. 2. Crystal structure of three O?Si trifluorosilanes
T2 - Journal of Structural Chemistry
AU - Ovchinnikov, Yu. E.
AU - Mozzhukhin, A O
AU - Antipin, M. Yu.
AU - Struchkov, Yu. T.
AU - Baryshok, V P
AU - Lazareva, N F
AU - Voronkov, M. G.
PY - 1994
DA - 1994/01/01
PB - Pleiades Publishing
SP - 888-894
IS - 6
VL - 34
SN - 0022-4766
SN - 1573-8779
ER -
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@article{1994_Ovchinnikov,
author = {Yu. E. Ovchinnikov and A O Mozzhukhin and M. Yu. Antipin and Yu. T. Struchkov and V P Baryshok and N F Lazareva and M. G. Voronkov},
title = {Influence of valence environment on the O?Si bond in pentacoordinated silicon compounds. 2. Crystal structure of three O?Si trifluorosilanes},
journal = {Journal of Structural Chemistry},
year = {1994},
volume = {34},
publisher = {Pleiades Publishing},
month = {jan},
url = {https://doi.org/10.1007/bf00752862},
number = {6},
pages = {888--894},
doi = {10.1007/bf00752862}
}
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Ovchinnikov, Yu. E., et al. “Influence of valence environment on the O?Si bond in pentacoordinated silicon compounds. 2. Crystal structure of three O?Si trifluorosilanes.” Journal of Structural Chemistry, vol. 34, no. 6, Jan. 1994, pp. 888-894. https://doi.org/10.1007/bf00752862.