Reaction of 2-substituted 5,5-dimethyl-4-oxo-1-pyrroline-1-oxides with nucleophilic reagents and synthesis of nitroxyl radicals?derivatives of pyrrolidine
Publication type: Journal Article
Publication date: 1990-02-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The reaction of β-oxonitrones, derivatives of pyrroline, with nitrogeneous nucleophiles and NaBH4 proceeds at the carbonyl group with the retention of the nitrone group. The reaction with organomagnesium and organolithium compounds takes place at the nitrone group with the retention of the carbonyl group, while the oxidation of the products formed proceeds to form nitroxyl radicals—Derivatives of pyrrolidin-4-one, which were used in the synthesis of spin-labeled dioximes.
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Reznikov V., Volodarskii L. B. Reaction of 2-substituted 5,5-dimethyl-4-oxo-1-pyrroline-1-oxides with nucleophilic reagents and synthesis of nitroxyl radicals?derivatives of pyrrolidine // Russian Chemical Bulletin. 1990. Vol. 39. No. 2. pp. 329-334.
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Reznikov V., Volodarskii L. B. Reaction of 2-substituted 5,5-dimethyl-4-oxo-1-pyrroline-1-oxides with nucleophilic reagents and synthesis of nitroxyl radicals?derivatives of pyrrolidine // Russian Chemical Bulletin. 1990. Vol. 39. No. 2. pp. 329-334.
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TY - JOUR
DO - 10.1007/bf00960663
UR - https://doi.org/10.1007/bf00960663
TI - Reaction of 2-substituted 5,5-dimethyl-4-oxo-1-pyrroline-1-oxides with nucleophilic reagents and synthesis of nitroxyl radicals?derivatives of pyrrolidine
T2 - Russian Chemical Bulletin
AU - Reznikov, V.A.
AU - Volodarskii, L B
PY - 1990
DA - 1990/02/01
PB - Springer Nature
SP - 329-334
IS - 2
VL - 39
SN - 1066-5285
SN - 1573-9171
ER -
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@article{1990_Reznikov,
author = {V.A. Reznikov and L B Volodarskii},
title = {Reaction of 2-substituted 5,5-dimethyl-4-oxo-1-pyrroline-1-oxides with nucleophilic reagents and synthesis of nitroxyl radicals?derivatives of pyrrolidine},
journal = {Russian Chemical Bulletin},
year = {1990},
volume = {39},
publisher = {Springer Nature},
month = {feb},
url = {https://doi.org/10.1007/bf00960663},
number = {2},
pages = {329--334},
doi = {10.1007/bf00960663}
}
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MLA
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Reznikov, V.A., and L B Volodarskii. “Reaction of 2-substituted 5,5-dimethyl-4-oxo-1-pyrroline-1-oxides with nucleophilic reagents and synthesis of nitroxyl radicals?derivatives of pyrrolidine.” Russian Chemical Bulletin, vol. 39, no. 2, Feb. 1990, pp. 329-334. https://doi.org/10.1007/bf00960663.