Effect of pressure on retention factors in HPLC using a non-porous stationary phase
Publication type: Journal Article
Publication date: 2002-01-01
scimago Q3
wos Q4
SJR: 0.278
CiteScore: 2.7
Impact factor: 1.3
ISSN: 00095893, 16121112
Organic Chemistry
Biochemistry
Clinical Biochemistry
Analytical Chemistry
Abstract
Pressure and temperature have significant influence on retention in HPLC. This study investigates the effect of pressure and temperature on the retention behavior of aromatic hydrocarbons (toluene, ethyl benzene, butyl benzene, pentyl benzene) and polar, acidic and basic samples (phenol, acetophenone, N,N-dimethyl aniline, benzophenone) on a reversed phase column. The effect has been studied on non-porous, tetradecyl (C14) coated silica particles. We found that the adsorption-induced decrease of the partial molar volume of the solutes investigated was between ΔV m =5–15 cm3 mol−1. The increment of the decrease of the partial molar volume due to the addition of one CH2 group, for the homologous series of the aromatic hydrocarbons is approximately ΔV CH2 =2.3 cm3mol−1.
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Total citations:
28
Citations from 2025:
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(7.14%)
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GOST
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Felinger A., Boros B., Ohmacht R. Effect of pressure on retention factors in HPLC using a non-porous stationary phase // Chromatographia. 2002. Vol. 56. No. 1. p. S61-S64.
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Felinger A., Boros B., Ohmacht R. Effect of pressure on retention factors in HPLC using a non-porous stationary phase // Chromatographia. 2002. Vol. 56. No. 1. p. S61-S64.
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RIS
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TY - JOUR
DO - 10.1007/bf02494114
UR - https://doi.org/10.1007/bf02494114
TI - Effect of pressure on retention factors in HPLC using a non-porous stationary phase
T2 - Chromatographia
AU - Felinger, A
AU - Boros, B.
AU - Ohmacht, R
PY - 2002
DA - 2002/01/01
PB - Springer Nature
SP - S61-S64
IS - 1
VL - 56
SN - 0009-5893
SN - 1612-1112
ER -
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BibTex (up to 50 authors)
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@article{2002_Felinger,
author = {A Felinger and B. Boros and R Ohmacht},
title = {Effect of pressure on retention factors in HPLC using a non-porous stationary phase},
journal = {Chromatographia},
year = {2002},
volume = {56},
publisher = {Springer Nature},
month = {jan},
url = {https://doi.org/10.1007/bf02494114},
number = {1},
pages = {S61--S64},
doi = {10.1007/bf02494114}
}
Cite this
MLA
Copy
Felinger, A., et al. “Effect of pressure on retention factors in HPLC using a non-porous stationary phase.” Chromatographia, vol. 56, no. 1, Jan. 2002, pp. S61-S64. https://doi.org/10.1007/bf02494114.