New methodology for synthesizing polypropylene-graft-polystyrene (PP-g-PS) by coupling reaction with brominated polypropylene
Nobuo KAWAHARA
1
,
Junji Saito
1
,
Shingo Matsuo
1
,
Hideyuki Kaneko
1
,
Tomoaki Matsugi
1
,
Shin-ichi Kojoh
1
,
Norio Kashiwa
1
1
R&D Center, Mitsui Chemicals, Inc., Sodegaura-City, Chiba, Japan
|
Publication type: Journal Article
Publication date: 2007-03-23
scimago Q2
wos Q2
SJR: 0.658
CiteScore: 6.7
Impact factor: 4.0
ISSN: 01700839, 14362449
Materials Chemistry
General Chemistry
Condensed Matter Physics
Polymers and Plastics
Abstract
Polypropylene-graft-polystyrene (PP-g-PS) was synthesized by the coupling reaction of brominated polypropylene produced by metallocene-catalyzed copolymerization of propylene with 11-bromo-1-undecene and polystyryl lithium salts made by living anionic polymerization, for the first time. These structures were confirmed by 1H NMR analysis. TEM micrographs of PP-g-PS copolymers indicated the nanometer level microphase-separation morphology between the polypropylene segment and the polystyrene segment. Obtained PP-g-PS copolymers could work as an effective compatibilizer for PP and PS.
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16
Total citations:
16
Citations from 2024:
3
(18.75%)
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MLA
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GOST
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KAWAHARA N. et al. New methodology for synthesizing polypropylene-graft-polystyrene (PP-g-PS) by coupling reaction with brominated polypropylene // Polymer Bulletin. 2007. Vol. 59. No. 2. pp. 177-183.
GOST all authors (up to 50)
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KAWAHARA N., Saito J., Matsuo S., Kaneko H., Matsugi T., Kojoh S., Kashiwa N. New methodology for synthesizing polypropylene-graft-polystyrene (PP-g-PS) by coupling reaction with brominated polypropylene // Polymer Bulletin. 2007. Vol. 59. No. 2. pp. 177-183.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1007/s00289-007-0759-8
UR - https://doi.org/10.1007/s00289-007-0759-8
TI - New methodology for synthesizing polypropylene-graft-polystyrene (PP-g-PS) by coupling reaction with brominated polypropylene
T2 - Polymer Bulletin
AU - KAWAHARA, Nobuo
AU - Saito, Junji
AU - Matsuo, Shingo
AU - Kaneko, Hideyuki
AU - Matsugi, Tomoaki
AU - Kojoh, Shin-ichi
AU - Kashiwa, Norio
PY - 2007
DA - 2007/03/23
PB - Springer Nature
SP - 177-183
IS - 2
VL - 59
SN - 0170-0839
SN - 1436-2449
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2007_KAWAHARA,
author = {Nobuo KAWAHARA and Junji Saito and Shingo Matsuo and Hideyuki Kaneko and Tomoaki Matsugi and Shin-ichi Kojoh and Norio Kashiwa},
title = {New methodology for synthesizing polypropylene-graft-polystyrene (PP-g-PS) by coupling reaction with brominated polypropylene},
journal = {Polymer Bulletin},
year = {2007},
volume = {59},
publisher = {Springer Nature},
month = {mar},
url = {https://doi.org/10.1007/s00289-007-0759-8},
number = {2},
pages = {177--183},
doi = {10.1007/s00289-007-0759-8}
}
Cite this
MLA
Copy
KAWAHARA, Nobuo, et al. “New methodology for synthesizing polypropylene-graft-polystyrene (PP-g-PS) by coupling reaction with brominated polypropylene.” Polymer Bulletin, vol. 59, no. 2, Mar. 2007, pp. 177-183. https://doi.org/10.1007/s00289-007-0759-8.