Polymer Bulletin

, том 79 , издание 2 , страницы 1239-1256

Structure of terminal units of polybutadiene synthesized via anionic mechanism

Тип публикации: Journal Article

Дата публикации: 2021-02-03

Springer Nature

Polymer Bulletin

scimago Q2

wos Q2

БС2

SJR: 0.658

CiteScore: 6.7

Impact factor: 4.0

ISSN: 01700839, 14362449

DOI: 10.1007/s00289-021-03549-5

Скопировать DOI

Materials Chemistry

General Chemistry

Condensed Matter Physics

Polymers and Plastics

Краткое описание

The structure of head and end groups of the polybutadiene synthesized by anionic polymerization of butadiene using tert-butyllithium as an initiator has been established using methods of NMR spectroscopy with T2-filter as well as 2D 1H, 13C HMBC and HSQC NMR spectroscopy. The spectral signals of head groups, which consist of tert-butyl groups connected with cis-1,4, trans-1,4 or 1,2-units of polybutadiene chain, were identified for the first time. A new method for the quantitative calculation of the content of head and end groups with different microstructures was proposed. It was shown that the total content of 1,4-units (both cis-1,4 and trans-1,4) in terminal groups is considerably higher than that in a main chain of polybutadiene.

Найдено

Топ-30

Журналы

	1
Polymer Chemistry	Polymer Chemistry, 1, 50% Polymer Chemistry 1 публикация, 50%
Russian Chemical Bulletin	Russian Chemical Bulletin, 1, 50% Russian Chemical Bulletin 1 публикация, 50%
	1

Издатели

	1
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 50% Royal Society of Chemistry (RSC) 1 публикация, 50%
Springer Nature	Springer Nature, 1, 50% Springer Nature 1 публикация, 50%
	1

Мы не учитываем публикации, у которых нет DOI.
Статистика публикаций обновляется еженедельно.

Вы ученый?

Создайте профиль, чтобы получать персональные рекомендации коллег, конференций и новых статей.

Войти с ORCID

Метрики

Цитировать

ГОСТ |

Цитировать

ГОСТ Скопировать

Rozentsvet V. A. et al. Structure of terminal units of polybutadiene synthesized via anionic mechanism // Polymer Bulletin. 2021. Vol. 79. No. 2. pp. 1239-1256.

ГОСТ со всеми авторами (до 50) Скопировать

Rozentsvet V. A., Sablina N. A., Ulyanova D. M., Kostjuk S. V., Tolstoy P. M. Structure of terminal units of polybutadiene synthesized via anionic mechanism // Polymer Bulletin. 2021. Vol. 79. No. 2. pp. 1239-1256.

RIS |

Цитировать

RIS Скопировать

TY - JOUR

DO - 10.1007/s00289-021-03549-5

UR - https://doi.org/10.1007/s00289-021-03549-5

TI - Structure of terminal units of polybutadiene synthesized via anionic mechanism

T2 - Polymer Bulletin

AU - Rozentsvet, Victor A

AU - Sablina, Nelly A

AU - Ulyanova, Daria M

AU - Kostjuk, Sergei V

AU - Tolstoy, Peter M

PY - 2021

DA - 2021/02/03

PB - Springer Nature

SP - 1239-1256

IS - 2

VL - 79

SN - 0170-0839

SN - 1436-2449

ER -

BibTex |

Цитировать

BibTex (до 50 авторов) Скопировать

@article{2021_Rozentsvet,

author = {Victor A Rozentsvet and Nelly A Sablina and Daria M Ulyanova and Sergei V Kostjuk and Peter M Tolstoy},

title = {Structure of terminal units of polybutadiene synthesized via anionic mechanism},

journal = {Polymer Bulletin},

year = {2021},

volume = {79},

publisher = {Springer Nature},

month = {feb},

url = {https://doi.org/10.1007/s00289-021-03549-5},

number = {2},

pages = {1239--1256},

doi = {10.1007/s00289-021-03549-5}

}

MLA

Цитировать

MLA Скопировать

Rozentsvet, Victor A., et al. “Structure of terminal units of polybutadiene synthesized via anionic mechanism.” Polymer Bulletin, vol. 79, no. 2, Feb. 2021, pp. 1239-1256. https://doi.org/10.1007/s00289-021-03549-5.