Role of cyclization in the degree-of-polymerization distribution of hyperbranched polymers
Тип публикации: Journal Article
Дата публикации: 1999-05-07
SCImago Q2
WOS Q2
БС2
SJR: 0.648
CiteScore: 8.4
Impact factor: 4.2
ISSN: 01700839, 14362449
Materials Chemistry
General Chemistry
Condensed Matter Physics
Polymers and Plastics
Краткое описание
A kinetic model of formation of hyperbranched polymers by step polyaddition of a BA f monomer including cyclization was developed. Reactions between acyclic-acyclic and acyclic-cyclic molecules and cyclization within acyclic molecules were considered. For cyclization within isomers of an x-mer, a bridging function between linear and spherical structures was used. Fractions of cyclic x-mers are predicted to increase with increasing degree of polymerization x and overall conversion of B groups. High fractions of cyclics were found in poly[2,2-bis(hydroxymethyl)propanoic acid] (poly (dimethylolpropionic acid)) by mass spectroscopy (ESI/FT MS) in a reasonable agreement with the model.
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ГОСТ
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Dušek K. et al. Role of cyclization in the degree-of-polymerization distribution of hyperbranched polymers // Polymer Bulletin. 1999. Vol. 42. No. 4. pp. 489-496.
ГОСТ со всеми авторами (до 50)
Скопировать
Dušek K., Šomvársky J., Smrčková M., Simonsick Jr W. J., Wilczek L. Role of cyclization in the degree-of-polymerization distribution of hyperbranched polymers // Polymer Bulletin. 1999. Vol. 42. No. 4. pp. 489-496.
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RIS
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TY - JOUR
DO - 10.1007/s002890050493
UR - https://doi.org/10.1007/s002890050493
TI - Role of cyclization in the degree-of-polymerization distribution of hyperbranched polymers
T2 - Polymer Bulletin
AU - Dušek, Karel
AU - Šomvársky, Ján
AU - Smrčková, Mirka
AU - Simonsick Jr, William J
AU - Wilczek, Lech
PY - 1999
DA - 1999/05/07
PB - Springer Nature
SP - 489-496
IS - 4
VL - 42
SN - 0170-0839
SN - 1436-2449
ER -
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BibTex (до 50 авторов)
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@article{1999_Dušek,
author = {Karel Dušek and Ján Šomvársky and Mirka Smrčková and William J Simonsick Jr and Lech Wilczek},
title = {Role of cyclization in the degree-of-polymerization distribution of hyperbranched polymers},
journal = {Polymer Bulletin},
year = {1999},
volume = {42},
publisher = {Springer Nature},
month = {may},
url = {https://doi.org/10.1007/s002890050493},
number = {4},
pages = {489--496},
doi = {10.1007/s002890050493}
}
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MLA
Скопировать
Dušek, Karel, et al. “Role of cyclization in the degree-of-polymerization distribution of hyperbranched polymers.” Polymer Bulletin, vol. 42, no. 4, May. 1999, pp. 489-496. https://doi.org/10.1007/s002890050493.
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