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Applied Physics A: Materials Science and Processing, volume 127, issue 8, publication number 584

Effect of Ba2+ doping on the structure and transport properties of Li6.28Al0.24La3Zr2O12 solid electrolyte

Publication typeJournal Article
Publication date2021-07-06
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor2.7
ISSN09478396, 14320630
General Chemistry
General Materials Science
Abstract
Garnet-structured solid electrolyte materials have drawn much attention due to their high ionic conductivity and electrochemical stability. Doping strategy is found to be very helpful in enhancing the performance of garnet-based solid electrolytes. In the present study, Li6.28Al0.24La3Zr2O12 with different amounts of Ba2+ doping at La3+ site is prepared with the help of solid-state reaction method. Li6.38Al0.24La2.9Ba0.1Zr2O12 sintered at 1000° C shows stabilization of cubic phase having closely packed grains with ionic conductivity of 0.46 × 10–4 S/cm at 25°C and activation energy of 0.29 eV. The presence of a well-defined thermally activated relaxation process in the prepared material is confirmed by the frequency-dependent electrical modulus and dielectric spectra.

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Sodhiya A. et al. Effect of Ba2+ doping on the structure and transport properties of Li6.28Al0.24La3Zr2O12 solid electrolyte // Applied Physics A: Materials Science and Processing. 2021. Vol. 127. No. 8. 584
GOST all authors (up to 50) Copy
Sodhiya A., Kumar R., Singh A. K., Soni S. Effect of Ba2+ doping on the structure and transport properties of Li6.28Al0.24La3Zr2O12 solid electrolyte // Applied Physics A: Materials Science and Processing. 2021. Vol. 127. No. 8. 584
RIS |
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RIS Copy
TY - JOUR
DO - 10.1007/s00339-021-04729-w
UR - https://doi.org/10.1007/s00339-021-04729-w
TI - Effect of Ba2+ doping on the structure and transport properties of Li6.28Al0.24La3Zr2O12 solid electrolyte
T2 - Applied Physics A: Materials Science and Processing
AU - Sodhiya, Anubha
AU - Kumar, Ranveer
AU - Singh, Arun Kumar
AU - Soni, Sunil
PY - 2021
DA - 2021/07/06 00:00:00
PB - Springer Nature
IS - 8
VL - 127
SN - 0947-8396
SN - 1432-0630
ER -
BibTex
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BibTex Copy
@article{2021_Sodhiya,
author = {Anubha Sodhiya and Ranveer Kumar and Arun Kumar Singh and Sunil Soni},
title = {Effect of Ba2+ doping on the structure and transport properties of Li6.28Al0.24La3Zr2O12 solid electrolyte},
journal = {Applied Physics A: Materials Science and Processing},
year = {2021},
volume = {127},
publisher = {Springer Nature},
month = {jul},
url = {https://doi.org/10.1007/s00339-021-04729-w},
number = {8},
doi = {10.1007/s00339-021-04729-w}
}
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