Nitroxide-mediated photo-controlled/living radical polymerization of ethyl acrylate
Publication type: Journal Article
Publication date: 2011-05-12
scimago Q2
wos Q3
SJR: 0.431
CiteScore: 4.5
Impact factor: 2.3
ISSN: 0303402X, 14351536
Materials Chemistry
Physical and Theoretical Chemistry
Colloid and Surface Chemistry
Polymers and Plastics
Abstract
The nitroxide-mediated photo-controlled/living radical polymerization of ethyl acrylate was attained using (2RS,2′RS)-azobis(4-methoxy-2,4-dimethylvaleronitrile) as the initiator, 4-methoxy-2,2,6,6-tetramethylpiperidine-1-oxyl as the mediator, and (4-tert-butylphenyl)diphenylsulfonium triflate as the photo-acid generator. The photopolymerization was performed in acetonitrile at room temperature by irradiation with a high-pressure mercury lamp. The molecular weight distribution of the resulting polymer decreased as the monomer concentration decreased. It was confirmed that the polymerization was controlled on the basis of the linear correlations for the first-order time-conversion plots and the plots of the molecular weight vs. the reciprocal of the initial concentration of the initiator, although the conversion–molecular weight plots did not show a completely linear correlation. The block copolymerization with methyl methacrylate accompanied by no deactivation of the growing polymer chain end supported the livingness of the polymerization.
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12
Total citations:
12
Citations from 2024:
1
(8.33%)
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GOST
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Yoshida E. Nitroxide-mediated photo-controlled/living radical polymerization of ethyl acrylate // Colloid and Polymer Science. 2011. Vol. 289. No. 10. pp. 1127-1132.
GOST all authors (up to 50)
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Yoshida E. Nitroxide-mediated photo-controlled/living radical polymerization of ethyl acrylate // Colloid and Polymer Science. 2011. Vol. 289. No. 10. pp. 1127-1132.
Cite this
RIS
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TY - JOUR
DO - 10.1007/s00396-011-2435-7
UR - https://doi.org/10.1007/s00396-011-2435-7
TI - Nitroxide-mediated photo-controlled/living radical polymerization of ethyl acrylate
T2 - Colloid and Polymer Science
AU - Yoshida, Eri
PY - 2011
DA - 2011/05/12
PB - Springer Nature
SP - 1127-1132
IS - 10
VL - 289
SN - 0303-402X
SN - 1435-1536
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2011_Yoshida,
author = {Eri Yoshida},
title = {Nitroxide-mediated photo-controlled/living radical polymerization of ethyl acrylate},
journal = {Colloid and Polymer Science},
year = {2011},
volume = {289},
publisher = {Springer Nature},
month = {may},
url = {https://doi.org/10.1007/s00396-011-2435-7},
number = {10},
pages = {1127--1132},
doi = {10.1007/s00396-011-2435-7}
}
Cite this
MLA
Copy
Yoshida, Eri. “Nitroxide-mediated photo-controlled/living radical polymerization of ethyl acrylate.” Colloid and Polymer Science, vol. 289, no. 10, May. 2011, pp. 1127-1132. https://doi.org/10.1007/s00396-011-2435-7.