Colloid and Polymer Science, volume 297, issue 3, pages 475-484

Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonic acid)–polymer composites as functional cathode binders for high power LiFePO 4 batteries

Publication typeJournal Article
Publication date2019-01-11
Quartile SCImago
Q2
Quartile WOS
Q3
Impact factor2.4
ISSN0303402X, 14351536
Materials Chemistry
Physical and Theoretical Chemistry
Colloid and Surface Chemistry
Polymers and Plastics
Abstract
Electroactive conductive composites based on poly(3,4-ethylenedioxythiophene):poly(styrenesulfonic acid) (PEDOT:PSS) and co-binding polymers—poly(ethylene oxide) (PEO) or sulfonated poly(phenylene oxide) (SPPO)—have been evaluated as conductive binders for LiFePO4 cathodes in Li-ion batteries. We have demonstrated that PEDOT:PSS–PEO and PEDOT:PSS–SPPO facilitated charge transfer for high rate application (discharge capacity up to 115 mAh g−1 at 3C). The thicker cathodes containing extra high loading of commercial LiFePO4/C (95 wt%, 19 mg cm−2) have exhibited specific capacity of up to 120 mAh g−1 and areal capacity of up to 2 mAh cm−2 at 1C, several times higher as compared to the earlier reported LiFePO4/PEDOT cathodes. While the application of PEO in PEDOT:PSS composites is restricted to sulfolane-based electrolytes due to solubility limitations, the PEDOT:PSS–SPPO-based cathodes can be used with conventional carbonate electrolytes, showing good stability and cyclability.

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Kubarkov A. V. et al. Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonic acid)–polymer composites as functional cathode binders for high power LiFePO 4 batteries // Colloid and Polymer Science. 2019. Vol. 297. No. 3. pp. 475-484.
GOST all authors (up to 50) Copy
Kubarkov A. V., Drozhzhin O. A., Karpushkin E. A., Stevenson K. J., Antipov E. V., Sergeyev V. G. Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonic acid)–polymer composites as functional cathode binders for high power LiFePO 4 batteries // Colloid and Polymer Science. 2019. Vol. 297. No. 3. pp. 475-484.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1007/s00396-018-04468-0
UR - https://doi.org/10.1007%2Fs00396-018-04468-0
TI - Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonic acid)–polymer composites as functional cathode binders for high power LiFePO 4 batteries
T2 - Colloid and Polymer Science
AU - Kubarkov, Aleksei V
AU - Drozhzhin, Oleg A
AU - Karpushkin, Evgeny A
AU - Stevenson, Keith J
AU - Antipov, Evgeny V.
AU - Sergeyev, Vladimir G.
PY - 2019
DA - 2019/01/11 00:00:00
PB - Springer Nature
SP - 475-484
IS - 3
VL - 297
SN - 0303-402X
SN - 1435-1536
ER -
BibTex |
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BibTex Copy
@article{2019_Kubarkov
author = {Aleksei V Kubarkov and Oleg A Drozhzhin and Evgeny A Karpushkin and Keith J Stevenson and Evgeny V. Antipov and Vladimir G. Sergeyev},
title = {Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonic acid)–polymer composites as functional cathode binders for high power LiFePO 4 batteries},
journal = {Colloid and Polymer Science},
year = {2019},
volume = {297},
publisher = {Springer Nature},
month = {jan},
url = {https://doi.org/10.1007%2Fs00396-018-04468-0},
number = {3},
pages = {475--484},
doi = {10.1007/s00396-018-04468-0}
}
MLA
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MLA Copy
Kubarkov, Aleksei V., et al. “Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonic acid)–polymer composites as functional cathode binders for high power LiFePO 4 batteries.” Colloid and Polymer Science, vol. 297, no. 3, Jan. 2019, pp. 475-484. https://doi.org/10.1007%2Fs00396-018-04468-0.
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