Microchimica Acta, volume 187, issue 11, publication number 610

Label-free silver triangular nanoplates for spectrophotometric determination of catecholamines and their metabolites

Zaytsev Valeriy D ¹

Furletov Aleksei A ¹

Apyari Vladimir ¹

Garshev Alexey V. ^{1, 2}

Dmitrienko Stanislava G ¹

Zolotov Yury A ^{1, 3}

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Department of Chemistry, Lomonosov Moscow State University, Moscow, Russia |

Department of Materials Science, Lomonosov Moscow State University, Moscow, Russia |

Kurnakov institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia |

Publication type: Journal Article

Publication date: 2020-10-15

Springer Nature

Journal: Microchimica Acta

Quartile SCImago

Quartile WOS

Impact factor: 5.7

ISSN: 00263672, 14365073

DOI: 10.1007/s00604-020-04576-1

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Analytical Chemistry

Abstract

A novel method towards spectrophotometric determination of catecholamines and their metabolites differing in their functional groups has been developed. This method is based on a change in morphology of silver triangular nanoplates upon the action of cateсholamines and their metabolites, which is manifested by the decrease of the nanoparticle local surface plasmon resonance (LSPR) band intensity or its shift to the short-wavelength region of the spectrum. The shift value of the LSPR band or the change of its intensity increases with increasing concentration of catecholamines or their metabolites, which is proposed for their spectrophotometric determination. The limits of detection of catecholamines and their metabolites under selected conditions increase in the series homovanillic acid < vanillylmandelic acid < L-epinephrine < L-norepinephrine < dopamine and are 0.25, 1.2, 3.0, 64, and 130 μmol L−1, respectively. The selectivity of the proposed method was assessed using vanillylmandelic acid as example. It was found that the determination of vanillylmandelic acid does is not interfered in the presence of 4000-fold excess of Na+, K+, CH3COO−, and 1000-fold excess of Mg2+, Ca2+, Al3+, NO3−. The method also allows for the selective determination of vanillylmandelic acid in the presence of a 1000-fold excess of structurally related substances that do not contain either a catechol fragment or an electron donor substituent. The proposed approach was successfully applied to the determination of catecholamines in pharmaceuticals and artificial urine. Graphical abstract Graphical abstract

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	1
Molecules	Molecules, 1, 12.5% Molecules 1 publication, 12.5%
Sensors and Actuators, B: Chemical	Sensors and Actuators, B: Chemical, 1, 12.5% Sensors and Actuators, B: Chemical 1 publication, 12.5%
Electrochimica Acta	Electrochimica Acta, 1, 12.5% Electrochimica Acta 1 publication, 12.5%
Journal of Saudi Chemical Society	Journal of Saudi Chemical Society, 1, 12.5% Journal of Saudi Chemical Society 1 publication, 12.5%
Comprehensive Reviews in Food Science and Food Safety	Comprehensive Reviews in Food Science and Food Safety, 1, 12.5% Comprehensive Reviews in Food Science and Food Safety 1 publication, 12.5%
Microchimica Acta	Microchimica Acta, 1, 12.5% Microchimica Acta 1 publication, 12.5%
Colloids and Surfaces A: Physicochemical and Engineering Aspects	Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1, 12.5% Colloids and Surfaces A: Physicochemical and Engineering Aspects 1 publication, 12.5%
Journal of Analytical Chemistry	Journal of Analytical Chemistry, 1, 12.5% Journal of Analytical Chemistry 1 publication, 12.5%
	1

Citations by publishers

	1 2 3
Elsevier	Elsevier, 3, 37.5% Elsevier 3 publications, 37.5%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 1, 12.5% Multidisciplinary Digital Publishing Institute (MDPI) 1 publication, 12.5%
King Saud University	King Saud University, 1, 12.5% King Saud University 1 publication, 12.5%
Wiley	Wiley, 1, 12.5% Wiley 1 publication, 12.5%
Springer Nature	Springer Nature, 1, 12.5% Springer Nature 1 publication, 12.5%
Pleiades Publishing	Pleiades Publishing, 1, 12.5% Pleiades Publishing 1 publication, 12.5%
	1 2 3

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Zaytsev V. D. et al. Label-free silver triangular nanoplates for spectrophotometric determination of catecholamines and their metabolites // Microchimica Acta. 2020. Vol. 187. No. 11. 610

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Zaytsev V. D., Furletov A. A., Apyari V., Garshev A. V., Dmitrienko S. G., Zolotov Y. A. Label-free silver triangular nanoplates for spectrophotometric determination of catecholamines and their metabolites // Microchimica Acta. 2020. Vol. 187. No. 11. 610

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RIS Copy

TY - JOUR

DO - 10.1007/s00604-020-04576-1

UR - https://doi.org/10.1007%2Fs00604-020-04576-1

TI - Label-free silver triangular nanoplates for spectrophotometric determination of catecholamines and their metabolites

T2 - Microchimica Acta

AU - Zaytsev, Valeriy D

AU - Apyari, Vladimir

AU - Garshev, Alexey V.

AU - Zolotov, Yury A

AU - Furletov, Aleksei A

AU - Dmitrienko, Stanislava G

PY - 2020

DA - 2020/10/15 00:00:00

PB - Springer Nature

IS - 11

VL - 187

SN - 0026-3672

SN - 1436-5073

ER -

BibTex

Cite this

BibTex Copy

@article{2020_Zaytsev,

author = {Valeriy D Zaytsev and Vladimir Apyari and Alexey V. Garshev and Yury A Zolotov and Aleksei A Furletov and Stanislava G Dmitrienko},

title = {Label-free silver triangular nanoplates for spectrophotometric determination of catecholamines and their metabolites},

journal = {Microchimica Acta},

year = {2020},

volume = {187},

publisher = {Springer Nature},

month = {oct},

url = {https://doi.org/10.1007%2Fs00604-020-04576-1},

number = {11},

doi = {10.1007/s00604-020-04576-1}

}

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Publisher

Springer Nature

Journal

Microchimica Acta

Quartile SCImago

Quartile WOS

Impact factor

5.7

ISSN

00263672 (Print)
14365073 (Electronic)

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Concentration Laboratory

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