Insertion of germylenes into Ge–X bonds giving molecular oligogermanes: theory and practice
K V Zaitsev
1
,
Oleg Kh Poleshchuk
2
Publication type: Journal Article
Publication date: 2019-09-27
scimago Q3
wos Q3
SJR: 0.321
CiteScore: 3.4
Impact factor: 1.9
ISSN: 00269247, 14344475
General Chemistry
Abstract
Insertion of a number of model germylenes (Me2Ge:, [Me2N]2Ge:, Cl2Ge:, MeN(CH2CH2O)2Ge:, MeN(CH2CH2NMe)2Ge:) into substituted germanes, H–GeR3 (R = Me, p-Tol, Ph, C6F5) and digermanes, R3Ge–GeR3 (R = Me, p-Tol, Ph, C6F5) to yield molecular oligogermanes was analyzed theoretically using density functional theory. All reactions were found to be thermodynamically favorable, but significant values of activation energy made these interactions less profitable. No interaction was observed in the reactions of (p-F3CC6H4)3GeH with [(Me3Si)2N]2Ge: and (C6F5)3GeGe(p-Tol)3 with [MeN(CH2CH2O)CH2CPh2O]Ge:. These results are important for understanding the main principles of the reactivity of group 14 element derivatives.
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Zaitsev K. V. et al. Insertion of germylenes into Ge–X bonds giving molecular oligogermanes: theory and practice // Monatshefte fur Chemie. 2019. Vol. 150. No. 10. pp. 1773-1778.
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Zaitsev K. V., Poleshchuk O. Kh. Insertion of germylenes into Ge–X bonds giving molecular oligogermanes: theory and practice // Monatshefte fur Chemie. 2019. Vol. 150. No. 10. pp. 1773-1778.
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TY - JOUR
DO - 10.1007/s00706-019-02495-3
UR - http://link.springer.com/10.1007/s00706-019-02495-3
TI - Insertion of germylenes into Ge–X bonds giving molecular oligogermanes: theory and practice
T2 - Monatshefte fur Chemie
AU - Zaitsev, K V
AU - Poleshchuk, Oleg Kh
PY - 2019
DA - 2019/09/27
PB - Springer Nature
SP - 1773-1778
IS - 10
VL - 150
SN - 0026-9247
SN - 1434-4475
ER -
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@article{2019_Zaitsev,
author = {K V Zaitsev and Oleg Kh Poleshchuk},
title = {Insertion of germylenes into Ge–X bonds giving molecular oligogermanes: theory and practice},
journal = {Monatshefte fur Chemie},
year = {2019},
volume = {150},
publisher = {Springer Nature},
month = {sep},
url = {http://link.springer.com/10.1007/s00706-019-02495-3},
number = {10},
pages = {1773--1778},
doi = {10.1007/s00706-019-02495-3}
}
Cite this
MLA
Copy
Zaitsev, K. V., et al. “Insertion of germylenes into Ge–X bonds giving molecular oligogermanes: theory and practice.” Monatshefte fur Chemie, vol. 150, no. 10, Sep. 2019, pp. 1773-1778. http://link.springer.com/10.1007/s00706-019-02495-3.
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