Evaluation of Activation Energies for Pairwise and Non-Pairwise Hydrogen Addition to Propyne Over Pd/Aluminosilicate Fiberglass Catalyst by Parahydrogen-Induced Polarization (PHIP)
Publication type: Journal Article
Publication date: 2014-09-10
scimago Q3
wos Q4
SJR: 0.308
CiteScore: 2.2
Impact factor: 1.1
ISSN: 09379347, 16137507
Atomic and Molecular Physics, and Optics
Abstract
Hydrogenation of propyne to propene over Pd/aluminosilicate fiberglass catalyst in the temperature range 175–350 °C was investigated with the use of parahydrogen-induced polarization (PHIP) technique. Activation energies for both pairwise and non-pairwise H2 addition routes were estimated. It was found that at 175–275 °C the activation energies for hydrogen addition to the triple bond of propyne have similar values (about 60–70 kJ/mol) for both routes of hydrogen addition. At higher temperatures (275–350 °C), the rate constant for pairwise hydrogen addition reaches a maximum value while the rate constant for non-pairwise hydrogen addition continues to increase with increasing temperature.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
|
|
|
Russian Chemical Reviews
2 publications, 22.22%
|
|
|
Chemistry - A European Journal
2 publications, 22.22%
|
|
|
Topics in Catalysis
1 publication, 11.11%
|
|
|
ACS Catalysis
1 publication, 11.11%
|
|
|
Journal of Physical Chemistry C
1 publication, 11.11%
|
|
|
Chemical Science
1 publication, 11.11%
|
|
|
Pure and Applied Chemistry
1 publication, 11.11%
|
|
|
1
2
|
Publishers
|
1
2
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
2 publications, 22.22%
|
|
|
Wiley
2 publications, 22.22%
|
|
|
American Chemical Society (ACS)
2 publications, 22.22%
|
|
|
Springer Nature
1 publication, 11.11%
|
|
|
Royal Society of Chemistry (RSC)
1 publication, 11.11%
|
|
|
Walter de Gruyter
1 publication, 11.11%
|
|
|
1
2
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
9
Total citations:
9
Citations from 2024:
1
(11.11%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Salnikov O. G. et al. Evaluation of Activation Energies for Pairwise and Non-Pairwise Hydrogen Addition to Propyne Over Pd/Aluminosilicate Fiberglass Catalyst by Parahydrogen-Induced Polarization (PHIP) // Applied Magnetic Resonance. 2014. Vol. 45. No. 10. pp. 1051-1061.
GOST all authors (up to 50)
Copy
Salnikov O. G., Barskiy D. A., Burueva D. B., Gulyaeva Y. K., Balzhinimaev B. S., Kovtunov K. V., Koptyug I. V. Evaluation of Activation Energies for Pairwise and Non-Pairwise Hydrogen Addition to Propyne Over Pd/Aluminosilicate Fiberglass Catalyst by Parahydrogen-Induced Polarization (PHIP) // Applied Magnetic Resonance. 2014. Vol. 45. No. 10. pp. 1051-1061.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1007/s00723-014-0586-7
UR - https://doi.org/10.1007/s00723-014-0586-7
TI - Evaluation of Activation Energies for Pairwise and Non-Pairwise Hydrogen Addition to Propyne Over Pd/Aluminosilicate Fiberglass Catalyst by Parahydrogen-Induced Polarization (PHIP)
T2 - Applied Magnetic Resonance
AU - Salnikov, Oleg G
AU - Barskiy, Danila A
AU - Burueva, Dudari B
AU - Gulyaeva, Yulia K
AU - Balzhinimaev, Bair S
AU - Kovtunov, Kirill V
AU - Koptyug, Igor V
PY - 2014
DA - 2014/09/10
PB - Springer Nature
SP - 1051-1061
IS - 10
VL - 45
SN - 0937-9347
SN - 1613-7507
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2014_Salnikov,
author = {Oleg G Salnikov and Danila A Barskiy and Dudari B Burueva and Yulia K Gulyaeva and Bair S Balzhinimaev and Kirill V Kovtunov and Igor V Koptyug},
title = {Evaluation of Activation Energies for Pairwise and Non-Pairwise Hydrogen Addition to Propyne Over Pd/Aluminosilicate Fiberglass Catalyst by Parahydrogen-Induced Polarization (PHIP)},
journal = {Applied Magnetic Resonance},
year = {2014},
volume = {45},
publisher = {Springer Nature},
month = {sep},
url = {https://doi.org/10.1007/s00723-014-0586-7},
number = {10},
pages = {1051--1061},
doi = {10.1007/s00723-014-0586-7}
}
Cite this
MLA
Copy
Salnikov, Oleg G., et al. “Evaluation of Activation Energies for Pairwise and Non-Pairwise Hydrogen Addition to Propyne Over Pd/Aluminosilicate Fiberglass Catalyst by Parahydrogen-Induced Polarization (PHIP).” Applied Magnetic Resonance, vol. 45, no. 10, Sep. 2014, pp. 1051-1061. https://doi.org/10.1007/s00723-014-0586-7.