Applied Magnetic Resonance, volume 50, issue 12, pages 1409-1418
51V and 25Mg NMR Study of the Kagome Staircase Compound Mg3V2O8
Publication type: Journal Article
Publication date: 2019-10-09
Journal:
Applied Magnetic Resonance
Quartile SCImago
Q4
Quartile WOS
Q4
Impact factor: 1
ISSN: 09379347, 16137507
Atomic and Molecular Physics, and Optics
Abstract
The 51V and 25Mg nuclear magnetic resonance (NMR) spectra have been obtained and magnetic susceptibility has been measured in polycrystalline Mg3V2O8. The analysis of 51V NMR spectra has shown that the line shift, δ(51V) = − 555 ppm, does not depend on temperature. It has been established that vanadium ions V5+ have a zero magnetic moment in this structure. The 25Mg NMR spectrum consists of two lines corresponding to two crystallographically nonequivalent positions of magnesium ions in the Kagome structure: Mg(1) are « spine » and Mg(2) are « cross tie » . Quadrupole frequencies and asymmetry parameters of 25Mg and 51V NMR spectra have been determined. The magnetic susceptibility is turn out to be zero (within the error) and remains constant over at a whole temperature range.
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American Chemical Society (ACS)
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American Chemical Society (ACS)
1 publication, 33.33%
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Ogloblichev V. V. et al. 51V and 25Mg NMR Study of the Kagome Staircase Compound Mg3V2O8 // Applied Magnetic Resonance. 2019. Vol. 50. No. 12. pp. 1409-1418.
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Ogloblichev V. V., Mikhalev K. N., Leonidova O. N., Arapova I. Yu., Germov A. Yu. 51V and 25Mg NMR Study of the Kagome Staircase Compound Mg3V2O8 // Applied Magnetic Resonance. 2019. Vol. 50. No. 12. pp. 1409-1418.
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TY - JOUR
DO - 10.1007/s00723-019-01165-1
UR - https://doi.org/10.1007%2Fs00723-019-01165-1
TI - 51V and 25Mg NMR Study of the Kagome Staircase Compound Mg3V2O8
T2 - Applied Magnetic Resonance
AU - Ogloblichev, V. V.
AU - Mikhalev, Konstantin N
AU - Leonidova, Olga N
AU - Arapova, Irina Yu
AU - Germov, Alexander Yu
PY - 2019
DA - 2019/10/09 00:00:00
PB - Springer Nature
SP - 1409-1418
IS - 12
VL - 50
SN - 0937-9347
SN - 1613-7507
ER -
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@article{2019_Ogloblichev,
author = {V. V. Ogloblichev and Konstantin N Mikhalev and Olga N Leonidova and Irina Yu Arapova and Alexander Yu Germov},
title = {51V and 25Mg NMR Study of the Kagome Staircase Compound Mg3V2O8},
journal = {Applied Magnetic Resonance},
year = {2019},
volume = {50},
publisher = {Springer Nature},
month = {oct},
url = {https://doi.org/10.1007%2Fs00723-019-01165-1},
number = {12},
pages = {1409--1418},
doi = {10.1007/s00723-019-01165-1}
}
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MLA
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Ogloblichev, V. V., et al. “51V and 25Mg NMR Study of the Kagome Staircase Compound Mg3V2O8.” Applied Magnetic Resonance, vol. 50, no. 12, Oct. 2019, pp. 1409-1418. https://doi.org/10.1007%2Fs00723-019-01165-1.