Applied Magnetic Resonance

, том 50 , издание 12 , страницы 1409-1418

51V and 25Mg NMR Study of the Kagome Staircase Compound Mg3V2O8

Тип публикации: Journal Article

Дата публикации: 2019-10-09

Springer Nature

Applied Magnetic Resonance

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SJR: 0.308

CiteScore: 2.2

Impact factor: 1.1

ISSN: 09379347, 16137507

DOI: 10.1007/s00723-019-01165-1

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Atomic and Molecular Physics, and Optics

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The 51V and 25Mg nuclear magnetic resonance (NMR) spectra have been obtained and magnetic susceptibility has been measured in polycrystalline Mg3V2O8. The analysis of 51V NMR spectra has shown that the line shift, δ(51V) = − 555 ppm, does not depend on temperature. It has been established that vanadium ions V5+ have a zero magnetic moment in this structure. The 25Mg NMR spectrum consists of two lines corresponding to two crystallographically nonequivalent positions of magnesium ions in the Kagome structure: Mg(1) are « spine » and Mg(2) are « cross tie » . Quadrupole frequencies and asymmetry parameters of 25Mg and 51V NMR spectra have been determined. The magnetic susceptibility is turn out to be zero (within the error) and remains constant over at a whole temperature range.

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Ceramics International	Ceramics International, 1, 20% Ceramics International 1 публикация, 20%
Magnetic Resonance in Chemistry	Magnetic Resonance in Chemistry, 1, 20% Magnetic Resonance in Chemistry 1 публикация, 20%
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Acta Materialia	Acta Materialia, 1, 20% Acta Materialia 1 публикация, 20%
Journal of Energy Storage	Journal of Energy Storage, 1, 20% Journal of Energy Storage 1 публикация, 20%
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Ogloblichev V. V. et al. 51V and 25Mg NMR Study of the Kagome Staircase Compound Mg3V2O8 // Applied Magnetic Resonance. 2019. Vol. 50. No. 12. pp. 1409-1418.

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Ogloblichev V. V., Mikhalev K. N., Leonidova O. N., Arapova I. Yu., Germov A. Yu. 51V and 25Mg NMR Study of the Kagome Staircase Compound Mg3V2O8 // Applied Magnetic Resonance. 2019. Vol. 50. No. 12. pp. 1409-1418.

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TY - JOUR

DO - 10.1007/s00723-019-01165-1

UR - https://doi.org/10.1007/s00723-019-01165-1

TI - 51V and 25Mg NMR Study of the Kagome Staircase Compound Mg3V2O8

T2 - Applied Magnetic Resonance

AU - Ogloblichev, V. V.

AU - Mikhalev, Konstantin N

AU - Leonidova, Olga N

AU - Arapova, Irina Yu

AU - Germov, Alexander Yu

PY - 2019

DA - 2019/10/09

PB - Springer Nature

SP - 1409-1418

IS - 12

VL - 50

SN - 0937-9347

SN - 1613-7507

ER -

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@article{2019_Ogloblichev,

author = {V. V. Ogloblichev and Konstantin N Mikhalev and Olga N Leonidova and Irina Yu Arapova and Alexander Yu Germov},

title = {51V and 25Mg NMR Study of the Kagome Staircase Compound Mg3V2O8},

journal = {Applied Magnetic Resonance},

year = {2019},

volume = {50},

publisher = {Springer Nature},

month = {oct},

url = {https://doi.org/10.1007/s00723-019-01165-1},

number = {12},

pages = {1409--1418},

doi = {10.1007/s00723-019-01165-1}

}

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Ogloblichev, V. V., et al. “51V and 25Mg NMR Study of the Kagome Staircase Compound Mg3V2O8.” Applied Magnetic Resonance, vol. 50, no. 12, Oct. 2019, pp. 1409-1418. https://doi.org/10.1007/s00723-019-01165-1.