Na3V2(PO4)3/C/Ag nanocomposite materials for Na-ion batteries obtained by the modified Pechini method
Andrey Chekannikov
1, 2
,
Roman Kapaev
3
,
Nataliya Tabachkova
4
,
Tatiana Kulova
2
,
Alexander Skundin
2
,
4
National University of Science and Technology, Moscow, Russia
|
Publication type: Journal Article
Publication date: 2017-02-14
scimago Q2
wos Q3
SJR: 0.552
CiteScore: 4.6
Impact factor: 2.6
ISSN: 14328488, 14330768
Electrochemistry
Condensed Matter Physics
General Materials Science
Electrical and Electronic Engineering
Abstract
Nanocomposite materials, Na3V2(PO4)3/C and Na3V2(PO4)3/C/Ag, were synthesized by a modified Pechini method. Their properties were characterized with the use of the X-ray diffraction analysis, scanning electron microscopy, transmission electron microscopy, thermogravimetric analysis, elemental analysis, Raman spectroscopy, impedance spectroscopy, and charge-discharge tests as cathode materials for sodium-ion batteries. The discharge capacity of Na3V2(PO4)3/C obtained at 600 °C was 116.1 and 75 mAh g−1 at a current density of 11 (0.1 C) and 110 mA g−1 (1 С) in the potential range of 2.7–3.8 V. The high capacity values for fast charge/discharge were achieved as a result of heat treatment by two steps and incorporation of appropriate amount of silver particles into Na3V2(PO4)3/C nanocomposite. The discharge capacities of thus obtained Na3V2(PO4)3/C with 0.2 wt% of Ag were 117.2, 112.5, and 83.5 mAh g−1 at the current densities of 11, 110, and 880 mA g−1. This experimental evidence reveals the great potential of NVP/C/Ag synthesized by the modified Pechini method as cathode materials for the production of sodium-ion batteries.
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Chekannikov A. et al. Na3V2(PO4)3/C/Ag nanocomposite materials for Na-ion batteries obtained by the modified Pechini method // Journal of Solid State Electrochemistry. 2017. Vol. 21. No. 6. pp. 1615-1624.
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Chekannikov A., Kapaev R., Novikova S., Tabachkova N., Kulova T., Skundin A., Yaroslavtsev A. Na3V2(PO4)3/C/Ag nanocomposite materials for Na-ion batteries obtained by the modified Pechini method // Journal of Solid State Electrochemistry. 2017. Vol. 21. No. 6. pp. 1615-1624.
Cite this
RIS
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TY - JOUR
DO - 10.1007/s10008-017-3524-4
UR - https://doi.org/10.1007/s10008-017-3524-4
TI - Na3V2(PO4)3/C/Ag nanocomposite materials for Na-ion batteries obtained by the modified Pechini method
T2 - Journal of Solid State Electrochemistry
AU - Chekannikov, Andrey
AU - Kapaev, Roman
AU - Novikova, Svetlana
AU - Tabachkova, Nataliya
AU - Kulova, Tatiana
AU - Skundin, Alexander
AU - Yaroslavtsev, Andrey
PY - 2017
DA - 2017/02/14
PB - Springer Nature
SP - 1615-1624
IS - 6
VL - 21
SN - 1432-8488
SN - 1433-0768
ER -
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@article{2017_Chekannikov,
author = {Andrey Chekannikov and Roman Kapaev and Svetlana Novikova and Nataliya Tabachkova and Tatiana Kulova and Alexander Skundin and Andrey Yaroslavtsev},
title = {Na3V2(PO4)3/C/Ag nanocomposite materials for Na-ion batteries obtained by the modified Pechini method},
journal = {Journal of Solid State Electrochemistry},
year = {2017},
volume = {21},
publisher = {Springer Nature},
month = {feb},
url = {https://doi.org/10.1007/s10008-017-3524-4},
number = {6},
pages = {1615--1624},
doi = {10.1007/s10008-017-3524-4}
}
Cite this
MLA
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Chekannikov, Andrey, et al. “Na3V2(PO4)3/C/Ag nanocomposite materials for Na-ion batteries obtained by the modified Pechini method.” Journal of Solid State Electrochemistry, vol. 21, no. 6, Feb. 2017, pp. 1615-1624. https://doi.org/10.1007/s10008-017-3524-4.