Journal of Solid State Electrochemistry, volume 25, issue 3, pages 789-796
The study of the pyrolysis products of Ni (II) and Pd (II) chelate complexes as catalysts for the oxygen electroreduction reaction
Belenov Sergey
1
,
Popov Leonid D
1
,
Kozakov Alexey T
2
,
Nikolsky Anatoly V
2
,
Safronenko Olga I
1
,
Nikulin Alexey Yu
1
Publication type: Journal Article
Publication date: 2020-11-01
Quartile SCImago
Q2
Quartile WOS
Q4
Impact factor: 2.5
ISSN: 14328488, 14330768
Electrochemistry
Condensed Matter Physics
General Materials Science
Electrical and Electronic Engineering
Abstract
Nitrogen-doped carbon materials were prepared by the pyrolysis of carbon black Vulcan XC-72 impregnated with nitrogen-containing Pd (II) and Ni (II) complexes. The composition of materials was studied at different stages of their synthesis. It is shown that nanoparticles of metals and/or their oxides are not the main electroactive component of materials in the oxygen electroreduction reaction (ORR). It is established that the palladium complex provides a much more efficient doping of carbon with nitrogen compared to the nickel complex of a similar composition. This results in the high ORR electrocatalytic activity of the catalyst obtained, palladium complex being used in an alkaline medium. This material is a promising one to be used as an electrocatalyst in fuel cells with an anion-conducting membrane. Graphical abstract Graphical abstract
Citations by journals
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1
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Russian Chemical Reviews
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Russian Chemical Reviews
1 publication, 33.33%
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ACS Omega
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ACS Omega
1 publication, 33.33%
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1
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Citations by publishers
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1
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 33.33%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
1 publication, 33.33%
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1
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Belenov S. et al. The study of the pyrolysis products of Ni (II) and Pd (II) chelate complexes as catalysts for the oxygen electroreduction reaction // Journal of Solid State Electrochemistry. 2020. Vol. 25. No. 3. pp. 789-796.
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Belenov S., Guterman V. E., Popov L. D., Kozakov A. T., Nikolsky A. V., Danilenko M. V., Safronenko O. I., Nikulin A. Yu. The study of the pyrolysis products of Ni (II) and Pd (II) chelate complexes as catalysts for the oxygen electroreduction reaction // Journal of Solid State Electrochemistry. 2020. Vol. 25. No. 3. pp. 789-796.
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TY - JOUR
DO - 10.1007/s10008-020-04854-1
UR - https://doi.org/10.1007%2Fs10008-020-04854-1
TI - The study of the pyrolysis products of Ni (II) and Pd (II) chelate complexes as catalysts for the oxygen electroreduction reaction
T2 - Journal of Solid State Electrochemistry
AU - Belenov, Sergey
AU - Guterman, Vladimir E
AU - Popov, Leonid D
AU - Kozakov, Alexey T
AU - Nikolsky, Anatoly V
AU - Danilenko, Maria V
AU - Safronenko, Olga I
AU - Nikulin, Alexey Yu
PY - 2020
DA - 2020/11/01 00:00:00
PB - Springer Nature
SP - 789-796
IS - 3
VL - 25
SN - 1432-8488
SN - 1433-0768
ER -
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@article{2020_Belenov,
author = {Sergey Belenov and Vladimir E Guterman and Leonid D Popov and Alexey T Kozakov and Anatoly V Nikolsky and Maria V Danilenko and Olga I Safronenko and Alexey Yu Nikulin},
title = {The study of the pyrolysis products of Ni (II) and Pd (II) chelate complexes as catalysts for the oxygen electroreduction reaction},
journal = {Journal of Solid State Electrochemistry},
year = {2020},
volume = {25},
publisher = {Springer Nature},
month = {nov},
url = {https://doi.org/10.1007%2Fs10008-020-04854-1},
number = {3},
pages = {789--796},
doi = {10.1007/s10008-020-04854-1}
}
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MLA
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Belenov, Sergey, et al. “The study of the pyrolysis products of Ni (II) and Pd (II) chelate complexes as catalysts for the oxygen electroreduction reaction.” Journal of Solid State Electrochemistry, vol. 25, no. 3, Nov. 2020, pp. 789-796. https://doi.org/10.1007%2Fs10008-020-04854-1.