Synthesis of hydroxy-functionalized ultrahigh molecular weight polyethylene using fluorenylamidotitanium complex
Publication type: Journal Article
Publication date: 2017-11-16
scimago Q1
wos Q2
SJR: 0.814
CiteScore: 7.1
Impact factor: 4.0
ISSN: 02567679, 14396203
Organic Chemistry
General Chemical Engineering
Polymers and Plastics
Abstract
Copolymerizations of ethylene and 1-dodecene were conducted with a series of ansa-fluorenylamidodimethyltitanium complexes, [t-BuNSiMe2Flu]TiMe2 (1a), [t-BuNSiMe2(2,7-tBu2Flu)]TiMe2 (1b), and [(1-adamantyl)NSiMe2(2,7-tBu2Flu)]TiMe2 (1c) activated by modified methylaluminoxane. The activity increased by the introduction of the alkyl groups on the fluorenyl and amido ligands, and 1c produced the highest molecular weight copolymers. Complex 1c also promoted copolymerization of ethylene and iBu3Al protected 10-undecen-1-ol with high activity (~2000 kg·mol−1·h−1), affording hydroxy-functionalized ultrahigh molecular weight polyethylene. The hydroxy content of the copolymers obtained was controllable by changing comonomer feed ratio. The introduction of a small amount of hydroxy group can alter the surface properties of polyethylene.
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Citations from 2024:
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Song X. et al. Synthesis of hydroxy-functionalized ultrahigh molecular weight polyethylene using fluorenylamidotitanium complex // Chinese Journal of Polymer Science (English Edition). 2017. Vol. 36. No. 2. pp. 171-175.
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Song X., Ma Q., Yuan H., Cai Z. Synthesis of hydroxy-functionalized ultrahigh molecular weight polyethylene using fluorenylamidotitanium complex // Chinese Journal of Polymer Science (English Edition). 2017. Vol. 36. No. 2. pp. 171-175.
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TY - JOUR
DO - 10.1007/s10118-018-2046-6
UR - https://doi.org/10.1007/s10118-018-2046-6
TI - Synthesis of hydroxy-functionalized ultrahigh molecular weight polyethylene using fluorenylamidotitanium complex
T2 - Chinese Journal of Polymer Science (English Edition)
AU - Song, Xiang-Yang
AU - Ma, Qiong
AU - Yuan, Hao-Bo
AU - Cai, Zheng-guo
PY - 2017
DA - 2017/11/16
PB - Springer Nature
SP - 171-175
IS - 2
VL - 36
SN - 0256-7679
SN - 1439-6203
ER -
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BibTex (up to 50 authors)
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@article{2017_Song,
author = {Xiang-Yang Song and Qiong Ma and Hao-Bo Yuan and Zheng-guo Cai},
title = {Synthesis of hydroxy-functionalized ultrahigh molecular weight polyethylene using fluorenylamidotitanium complex},
journal = {Chinese Journal of Polymer Science (English Edition)},
year = {2017},
volume = {36},
publisher = {Springer Nature},
month = {nov},
url = {https://doi.org/10.1007/s10118-018-2046-6},
number = {2},
pages = {171--175},
doi = {10.1007/s10118-018-2046-6}
}
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MLA
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Song, Xiang-Yang, et al. “Synthesis of hydroxy-functionalized ultrahigh molecular weight polyethylene using fluorenylamidotitanium complex.” Chinese Journal of Polymer Science (English Edition), vol. 36, no. 2, Nov. 2017, pp. 171-175. https://doi.org/10.1007/s10118-018-2046-6.