Chinese Journal of Polymer Science (English Edition), volume 37, issue 12, pages 1200-1204
Synthesis of Polycarbonate Block Terpolymers Using Robust Cobalt Catalyst Systems
Publication type: Journal Article
Publication date: 2019-06-03
Q1
Q2
SJR: 0.881
CiteScore: 7.1
Impact factor: 4.1
ISSN: 02567679, 14396203
Organic Chemistry
General Chemical Engineering
Polymers and Plastics
Abstract
This contribution reports an efficient approach for preparing polycarbonate block terpolymers by immortal stepwise copolymerization of CO2 with different epoxides in the presence of enol chain transfer, mediated by robust cobalt catalyst systems consisting of the fluorine substituted salenCo(III)NO3 or biphenol-linker bimetallic Co(III) complex in conjunction with an ionic cocatalyst, PPNX (PPN = bis(triphenylphosphine)iminium, X = NO3− or 2,4-dinitrophenoxide). Various polycarbonate block terpolymers were obtained in perfectly unimodal distribution of their molecular weights with narrow polydispersity. They all possessed only one broad glass transition temperature, which could be adjusted by altering the length of different polycarbonate segments.
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GOST
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Jiang Y. J. et al. Synthesis of Polycarbonate Block Terpolymers Using Robust Cobalt Catalyst Systems // Chinese Journal of Polymer Science (English Edition). 2019. Vol. 37. No. 12. pp. 1200-1204.
GOST all authors (up to 50)
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Jiang Y. J., Ren W., Liu Y., Lu X. Synthesis of Polycarbonate Block Terpolymers Using Robust Cobalt Catalyst Systems // Chinese Journal of Polymer Science (English Edition). 2019. Vol. 37. No. 12. pp. 1200-1204.
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RIS
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TY - JOUR
DO - 10.1007/s10118-019-2270-8
UR - https://doi.org/10.1007/s10118-019-2270-8
TI - Synthesis of Polycarbonate Block Terpolymers Using Robust Cobalt Catalyst Systems
T2 - Chinese Journal of Polymer Science (English Edition)
AU - Jiang, Ying Jie
AU - Ren, Wei-Min
AU - Liu, Ye
AU - Lu, Xiao-Bing
PY - 2019
DA - 2019/06/03
PB - Springer Nature
SP - 1200-1204
IS - 12
VL - 37
SN - 0256-7679
SN - 1439-6203
ER -
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BibTex (up to 50 authors)
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@article{2019_Jiang,
author = {Ying Jie Jiang and Wei-Min Ren and Ye Liu and Xiao-Bing Lu},
title = {Synthesis of Polycarbonate Block Terpolymers Using Robust Cobalt Catalyst Systems},
journal = {Chinese Journal of Polymer Science (English Edition)},
year = {2019},
volume = {37},
publisher = {Springer Nature},
month = {jun},
url = {https://doi.org/10.1007/s10118-019-2270-8},
number = {12},
pages = {1200--1204},
doi = {10.1007/s10118-019-2270-8}
}
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MLA
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Jiang, Ying Jie, et al. “Synthesis of Polycarbonate Block Terpolymers Using Robust Cobalt Catalyst Systems.” Chinese Journal of Polymer Science (English Edition), vol. 37, no. 12, Jun. 2019, pp. 1200-1204. https://doi.org/10.1007/s10118-019-2270-8.